Aluminium manufacture (AQA GCSE C2 7.3)

The key ideas for the electrolysis of aluminium oxide

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What sort of bonding does aluminium oxide, Al2O3, have?
Ionic - it's a metal and a non-metal joined together
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Why does aluminium oxide have a high melting point?
It has strong forces of attraction between the oppositely charged ions
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Why can't solid aluminium oxide conduct electricity?
The ions are in fixed positions - they can't move
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Why can molten aluminium oxide conduct electricity?
The ions are free to move
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What is the role of the cryolite?
It lowers the melting point - so reducing electrical energy costs
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What is formed at the negative electrode?
Molten aluminium
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What is the half equation for the reaction at the negative electrode?
Al3+ + 3e --> Al
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Is the reaction at the negative electrode reduction or oxidation?
Reduction (OILRIG - reduction is gain of electrons)
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What is the positive electrode made of?
Graphite (carbon)
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What is formed at the positive electrode?
Oxygen gas
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What is the half equation for the reaction at the positive electrode?
2O2- -4e --> O2 OR 2O2- --> O2 + 4e
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Is the reaction at the positive electrode reduction or oxidation?
Oxidation (OILRIG - oxidation is loss of electrons)
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Why do the positive electrodes have to be replaced frequently?
The carbon reacts with the oxygen to form CO2, so the electrode wears away
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Other cards in this set

Card 2

Front

Why does aluminium oxide have a high melting point?

Back

It has strong forces of attraction between the oppositely charged ions

Card 3

Front

Why can't solid aluminium oxide conduct electricity?

Back

Preview of the front of card 3

Card 4

Front

Why can molten aluminium oxide conduct electricity?

Back

Preview of the front of card 4

Card 5

Front

What is the role of the cryolite?

Back

Preview of the front of card 5
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