Organic Synthesis A2 OCR A 0.0 / 5 ? ChemistryOrganic SynthesisA2/A-levelOCR Created by: chohanrCreated on: 25-01-20 19:32 Alkanes --> Haloalkane Cl2/Br2 UV Light (Free radical substitution) 1 of 29 Alkene --> Alkane H2 gas; Ni catalyst (reduction and addition) 2 of 29 Alkene --> Alcohol Steam (H2O(g)) ; concentrated H3PO4 catalyst (Electrophillic addition) 3 of 29 Alkene --> Haloalkane HCl/HBr (Electrophillic addition) 4 of 29 Alkene --> Haloalkane HCl/HBr (Electrophillic addition) 5 of 29 Alkene Monomers Addition Poly(alkene) (Addition polymerisation) 6 of 29 Haloalkane --> Alcohol NaOH/KOH in water solvent; heat under reflux (Nucleophillic substitution and Hydrolysis) 7 of 29 Haloalkane --> Primary amine NH3 in excess with ethanol solvent; high pressure (Nucleophillic substitution)a 8 of 29 Haloalkane --> Nitrile NaCN in H2SO4 (Nucleophillic substitution) 9 of 29 Alcohol --> Aldehyde Na2CrO7 in dilute H2SO4 ; heat and distil (Primary alcohol ONLY) (Oxidation) 10 of 29 Alcohol --> Carboxylic acid Na2Cr2O7 in dilute H2SO4 ; Heat under reflux (Primary alcohol (oxidation)ONLY) 11 of 29 Alcohol --> Ketone Na2Cr2O7 in dilute H2SO4 ; Heat under reflux (Seconadry alcohol (oxidation)ONLY) 12 of 29 Alcohol --> Haloalkane NaCl/NaBr/NaI in sulphuric acid (Substitution) 13 of 29 Alcohol --> Ester +Carboxylic acid ; H2SO4 catalyst (Esterification) 14 of 29 Alcohol --> Alkene Concentrated H2SO4 (Elimination or Dehydration) 15 of 29 Aldehyde/Ketone --> Hydroxynitrile NaCN or KCN in ethanol (Nucleophillic addition) 16 of 29 Aldehyde --> Primary alcohol NaBH4 (Reduction) 17 of 29 Ketone --> Seconary alcohol NaBH4 (Reduction) 18 of 29 Carboxylic acid --> Ester + Alcohol and Conc. H2SO4 catalyst 19 of 29 Carboxylic acid --> Sodium carboxylate salt Na/ NaOH/NaHCO3/Na2CO3 20 of 29 Carboxylic acid --> Acyl Chloride SOCl2 21 of 29 Ester --> Carboxylic acid and alcohol H2O with HCl catalyst (Acid hydrolysis) 22 of 29 Ester --> Carboxylate salt and alcohol dilute NaOH ; heat under reflux (Alkalis hydrolysis) 23 of 29 Acyl chloride --> Carboxylic acid H2O 24 of 29 Acyl chloride --> Primary amide NH3 25 of 29 Acyl chloride --> Seconadry amide + Primary amine 26 of 29 Acyl chloride --> Ester + Alcohol (Esterification) 27 of 29 Nitrile --> Amine H2 gas; Ni catalyst (Reduction) 28 of 29 Nitrile --> Carboxylic acid Dilute HCl; heat under reflux (Acid hydrolysis) 29 of 29
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