A molecule needs:
- a carbon-corbon double bond must be present (ALWAYS ALKENES)
- each carbon in the double bond must be attached to two different groups (eg H and Cl)
It is similar to cis-trans isomerism. Cis-trans isomerism is a special type of E/Z isomerism in which there is a non-hydrogen group and a hydrogen group on each C of C=C double bond.
In cis-trans isomerism:
- the cis isomer is the Z isomer ("zusammen" meaning together)
- the trans isomer is the E isomer ("entgegen" meaning opposite)
For example: C₂H₂Cl₂
has the isomers E-1,2-dichloroethene (trans - groups on opposite sides) and
Z-1,2-dichloroethene (cis - groups on the same side)
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