What's in a Medicine 13.2 Alcohols and Ethers

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  • Created by: Emily
  • Created on: 15-01-13 10:13
What are the functional groups of alcohols and ethers?
A have OH (hydroxyl), E have OR (alkoxy)
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What does polyhydric mean?
Substance contains more than one OH group
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When are isomeric alcohols possible?
With alcohols containing more than 2 C atoms
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Why can alcohol molecules form hydrogen bonds?
The molecules are polar due to the O—H
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Under what conditions do you oxidise alcohols?
Primary and secondary alcohols oxidise with acidified potassium dichromate (VI) where orange Chromate ions reduced to green Chromium ions.
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What products are formed when alcohols are oxidised?
Primary – carboxylic acid
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When will oxidation of an alcohol not take place?
When an H atom is not attached to a C to which the OH is attached
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What is formed when alcohols undergo dehydration? What type of reaction is this?
Corresponding alkene and water formed. Elimination (molecule of water removed)
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What conditions are needed?
Alcohol in vaporous state, aluminium oxide catalyst at 300oC or hear with conc. H2SO4
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Are ethers polar? Why are ether molecules unable to form hydrogen bonds?
Only slightly so they are only slightly soluble in water. There are no H atoms attached to the O
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Which ethers are very volatile and flammable?
The ‘lower’ ethers, i.e. less carbon atoms
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Other cards in this set

Card 2

Front

What does polyhydric mean?

Back

Substance contains more than one OH group

Card 3

Front

When are isomeric alcohols possible?

Back

Preview of the front of card 3

Card 4

Front

Why can alcohol molecules form hydrogen bonds?

Back

Preview of the front of card 4

Card 5

Front

Under what conditions do you oxidise alcohols?

Back

Preview of the front of card 5
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