AQA A Level Mechanism and Conditions Summary 5.0 / 5 based on 4 ratings ? ChemistrySynthetic routesA2/A-levelAQA Created by: mitzi lipardoCreated on: 25-03-15 14:44 ALKANE -> HALOALKANE Br2, Cl2; UV light; Free Radical Sub. 1 of 27 HALOALKANE -> ALCOHOL KOH AQUEOUS; heat under reflux; Nucleophilic Sub. 2 of 27 HALOALKANE -> ALKENE KOH ALCOHOLIC; heat under reflux; Elimination 3 of 27 HALOALKANE -> NITRILE KCN in ETHANOL; heat under reflux; Nucleophilic Sub. 4 of 27 HALOALKANE -> Primary AMINE Alcoholic NH3; heat under pressure; Nucleophilic Sub. 5 of 27 NITRILE -> Primary AMINE LiAlH4 in ETHER; REDUCTION 6 of 27 ALKENE -> HALOALKANE HBr, HCl; room temp; Eletrophilic Add. 7 of 27 ALKENE -> DIHALOALKANE Br2, Cl2; room temp; Electrophilic Add. 8 of 27 DIHALOALKANE -> DIOL KOH aqueous; heat under reflux; Nucleophilic Sub. 9 of 27 Primary AMINE -> Secondary/Tertiary AMINE/Quarternary SALT Haloalkane; Nucleophilic Subsitution 10 of 27 Primary AMINE -> Secondary AMIDE Acy chloride; room temp; Nucleophilic Addition/Elimination 11 of 27 ALKENE -> poly(ALKENE) high pressure; catalyst 12 of 27 ALKENE -> ALCOHOL 1) H2SO4; Electrophilic Addition 2) H2O; warm; Hydrolysis 13 of 27 ALCOHOL -> ALKENE conc. H2SO4/ conc. H3PO4; Elimination, Dehydration 14 of 27 ALCOHOL -> ESTER Carboxylic Acid + H2SO4; heat; ESTERIFICATION 15 of 27 ALCOHOL -> ALDEHYDE (primary alcohol only) Na2Cr2O7/H+; heat & distil; PARTIAL OXIDATION 16 of 27 ALCOHOL -> KETONE (secondary alcohol only) Na2Cr2O7; heat; OXIDATION 17 of 27 ALDEHYDE -> ALCOHOL NaBH4; Reduction; Nucleophilic Add 18 of 27 KETONE -> ALCOHOL NaBH4; Reduction; Nucleophilic Add 19 of 27 ALDEHYDE or KETONE -> HYDROXYNITRILE NaCN + H2SO4; Nucleophilic Add 20 of 27 ALDEHYDE -> CARBOXYLIC ACID (primary alcohol only) Na2Cr2O7/H+; heat under reflux + excess oxidising agent; OXIDATION 21 of 27 CARBOXYLIC ACID -> ESTER Alcohol + H2SO4; heat; ESTERIFICATION 22 of 27 ACYL CHLORIDE/ACID ANHYDRIDE -> Primary AMIDE NH3; room temp; Nucleophilic Addition/Elimination 23 of 27 ACYL CHLORIDE/ACID ANHYDRIDE -> Secondary AMIDE Primary Amine; room temp; Nucleophilic Addition/Elimination 24 of 27 ACYL CHLORIDE/ACID ANHYDRIDE -> ESTER Alcohol; room temp; Nucleophilic Add/Elimination 25 of 27 ACYL CHLORIDE/ACID ANHYDRIDE -> CARBOXYLIC ACID H2O; room temp; Nucleophilic Addition/Elimination 26 of 27 Esters and Amides can be hydrolysed by ____ and ____ NaOH and acids 27 of 27
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