F324 Unit 4: Arenes
- Created by: Saoirse
- Created on: 07-06-14 19:52
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Arene: aromatic hydrocarbon. Aromatic: ring structure
Benzene
Molecular formula: C6H6
Kekule structure: alternate single and double C bonds
Delocalised: Ring of delocalised electrons formed above C planes due to the overlap of p orbitals. Overlap produces a series of pi bonds spread across all 6 C.
- Evidence for delocalised structure not kekule:
- C-C bond lengths in benzene are all the same intermediate length but C-C and C=C have a different length so can't be kekule (seen in x ray crystallography)
- Benzene does not decolourise Br water, should happen if C=C present
- Hydrogenation for benzene should be 3x Cyclohexene if kekule structure but in reality is is much lower than expected
Benzene's reactions - Electrophilic substitution
Nitration - conc H2SO4 catalyst at 50 degrees/ Halpgenation - halogen carrier (FeCl3/AlCl3/Fe)
Reactivity
Cyclohexane decolourises Br water…
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