Allotropes of carbon

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  • Created by: Mai01
  • Created on: 01-05-17 11:52

Allotropes of carbon

Allotropes:

Different structural forms of the same element 

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Fullerenes

  • A Fullerene is a simple molecule
  • It is formed when each carbon atom is covalently bonded with three other carbon atoms.
  • Often forms tubular molecules(nanotubes) or spherical structures (Buckminister fullerene-C60 i.e 60 carbon atoms forms a ball)
  • Weak intermolecular forces having low melting points.
  • Weak forces makes them soft + slippery (Lubricant)
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Graphene

  • It is not a simple molecule
  • Consists of a sheet of carbon with no fixed formula.
  • Sheet is one atom thick--making it very light
  • covalently bonded--making it extremely strong
  • Allows electrons to freely move across its surface--making it a good electrical conductor
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Graphite

  • Giant molecular covalent structure
  • 3D networks of carbons covalently bonded
  • Each carbon atom is covalently bonded with 3 carbon atoms forming a hexagonal sheet
  • sheets are held together by weak forces of attraction allowing the layers to slide past each other-- making it a good lubricant(soft/slippery)
  • Layered stucture--so not all of the electrons are covalently bonded. Delocalised electrons are free to move to carry electron--conducts electricity--used as electrodes
  • High melting points due to strong covalent bonds
  • Cheap and very unreactive
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diamond

  • Giant molecular covalent structure
  • 3D rigid network of carbon atoms in a tetrahedral arrangement
  • Each carbon atom is covalently bonded with 4 other carbon atoms
  • Strong covalent bonds having high melting points
  • No charged particles/delocalised electrons so it is a good elecrical insulator
  • Strong so its useful for cutting tools.
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