thermodynamics

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  • Created by: anna888
  • Created on: 02-02-23 12:33
what is first law of thermodynamics
energy cant be created or destroyed, just moved from one form to another
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features of exothermic reaction
change that releases heat, decrease in enthalpy, delta h is negative
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features of endothermic reaction
change that requires heat, increase in enthalpy, delta h is positive
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define enthaply
a state function, which quanitifies heat flow in or out of a system at constant pressure
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enthalpy equation
delta H= delta H products- delta H reactants. KJmol
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define a state function
function where the value only depends on the present state, not on the steps taken to reach that state
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what is hesses law. what is used to calculate
the total enthalpy for a reation is equal to the sum of the enthalpy chnages for the indivudal steps. enthalpy of formation
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define enthalpy of formation
heat changes wen 1 mol of a compound is formed from its elements at 1atm. zero for uncombined elements
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define entropy
measure of randomness in a system
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entropy equation. units?
delta s = s final - s inital. JKmol
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rank liquid gas solid as increaasing entropy
solid least. gas most
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what is the 2nd law of thermodynamics
the entropy of a universe increases spontaneously and remains unchanged in equilibrium
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what is equation that represents 2nd law of thermodynamics
delta s= q (rev)/ T
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what effect does a exothermic vs endothermic reaction have on enthalpy
exo increases it, endo decreases it
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whats the third law of thermodynamics
the entropy of a perfectly ordered crystaline substance at 0K is zero
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how to calculate equib conc
conc of products/conc of reactants
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what is delta G equib equation
delta G= RTlogK
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what does postive delta G vs negative mean
positive means reaction is not sponteaneous and happens only with energy input, negative delta G means reaction is spontaneous
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what does a K value larger than one mean
reaction more to rhs, products lower in energy
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what is equation linking enthalpy entropy and energy
delta G= delta H- T delta S
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thermodynamics vs kenetics
thermodynamics is assosiated with equilbria, kenetics is assosiated with rate
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Card 2

Front

features of exothermic reaction

Back

change that releases heat, decrease in enthalpy, delta h is negative

Card 3

Front

features of endothermic reaction

Back

Preview of the front of card 3

Card 4

Front

define enthaply

Back

Preview of the front of card 4

Card 5

Front

enthalpy equation

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