Organic Synthesis Reactions A2 5.0 / 5 based on 4 ratings ? ChemistryOrganic ChemistryA2/A-levelAQA Created by: BethcrCreated on: 26-01-15 10:33 Ketone to Hydroxynitrile Nucleophilic Addition KCN/H2SO4 Mechanism Needed 1 of 23 Aldehyde to Hydroxynitrile Nucleophilic Addition KCN/H2SO4 Mechanism needed 2 of 23 Carboxylic Acid to Acid Anhydride P4O10 3 of 23 Acid Anhydride to Carboxylic Acid Nucleophilic Addition-Elimination H2O 4 of 23 Carboxylic Acid to Ester Nucleophilic Addition-Elimination (Esterification/Condensation) Alcohol 5 of 23 Ester to Carboxylic Acid Hydrolysis 1. HCl/H2SO4 dilute, reflux 2. NaOH(aq) distillation then HCl/H2SO4(aq) and distillation 6 of 23 Acid Anhydride to Ester Nucleophilic Addition-Elimination Ethanol 7 of 23 Ester to Alcohol Hydrolysis 1.HCl/H2SO4 dilute,reflux 2.NaOH(aq) then distillation 8 of 23 Alcohol to Ester Nucleophilic Addition-Elimination (Esterification/Condensation) Carboxylic Acid 9 of 23 Carboxylic Acid to Acyl Chloride PCl5 10 of 23 Acyl Chloride to Carboxylic Acid Nucleophilic Addition-Elimination H2O Mechanism Needed 11 of 23 Acyl Chloride to N-substituted Amide Nucleophilic Addition-Elimination Primary Amine Mechanism Needed 12 of 23 Acid Anhydride to N-substituted amide Nucleophilic Addition-Elimination Primary Amine 13 of 23 Acyl Chloride to Amide Nucleophilic Addition-Elimination NH3 Mechanism Needed 14 of 23 Acid anhydride to Amide Nucleophilic Addition-Elimination 15 of 23 Acyl Chloride to Ester Nucleophilic Addition-Elimination Alcohol Mechanism Needed 16 of 23 Nitrile to Primary Amine Reduction 1.LiAlH4 2.H2 Ni catalyst 17 of 23 Primary Amine to Secondary Amine Nucleophilic Substitution Primary Amine Mechanism needed 18 of 23 Secondary Amine to Tertiary Amine Nucleophilic Substitution - Primary Amine Mechanism needed 19 of 23 Tertiary Amine to Quaternary Ammonium Salt Nucleophilic Substitution - Primary Amine Mechanism needed 20 of 23 Haloalkane to Quaternary Ammonium Salt Nucleophilic Substitution - Tertiary Amine Mechanism needed 21 of 23 Haloalkane to Tertiary Amine Nucleophilic Substitution - Secondary Amine Mechanism Needed 22 of 23 Haloalkane to Secondary Amine Nucleophilic Substitution - Primary Amine Mechanism needed 23 of 23
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