AS Physical Chemistry Revision

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What are standard conditions?
298K and 100kPa
1 of 13
Define the term Standard Enthalpy of Formation.
The enthalpy change when one mole of a compound is formed from its elements under standard conditions.
2 of 13
What is the standard enthalpy change of combustion of 37g of 2-chlorobutane that heats 2.5dm3 of water from 20'C to 41.5'C?
-5644kJmol-1
3 of 13
What is the standard enthalpy change of neutralisation of 37g of 50 cm3 of 1mol dm3 HCl and 50 cm3 of 1 mol dm3 H2SO4 when the temperature of the solution rises by 16’C?
-134.4 kJmol-1
4 of 13
Given that ΔH°c of S is – 442.6 kJmol-1, ΔH°c of H2 is – 285.8 kJmol-1 and ΔH°c of H2S is – 519.1 kJmol-1, find the standard enthalpy change of formation of hydrogen sulfide.
-209.3 kJmol-1
5 of 13
Given that ΔH°f of NaOH is – 426.7 kJmol-1, ΔH°f of NaBr is – 361.1 kJmol-1, ΔH°f of NaBrO3 is – 334.1 kJmol-1 and ΔH°f of H2O is – 285.8 kJmol-1, find the standard enthalpy change of the following reaction: 3Br2 + 6NaOH → 5NaBr + NaBrO3 + 3H2O.
-436.8 kJmol-1
6 of 13
Given that C-H = 413kJmol-1, C-C = 347kJmol-1, C-Cl = 243kJmol-1, O-H = 463 kJmol-1, C-O = 805 kJmol-1 and H-Cl = 432 kJmol-1, find the enthalpy change of CH3CH2Cl + H2O → CH3CH2OH + HCl.
-184 kJmol-1
7 of 13
Define the term Average bond enthalpy.
The energy required to break one mole of a given bond averaged over many compounds.
8 of 13
How does a homogenous catalyst provide a pathway of lower activation energy?
Forms an intermediate
9 of 13
What is the difference in the energy profile diagram for a reaction with a catalyst and one without?
Lower peak
10 of 13
Define the term Equilibrium.
A reversible reaction in which the amount of each reactant / product remains constant.
11 of 13
Write an expression for Kc for the following reversible reaction: 2NO (g) + O2 (g) -> N2O4 (g).
mol2dm-6
12 of 13
Which is NOT a condition for the modern haber process?
Equal concentration of reactants and products
13 of 13

Other cards in this set

Card 2

Front

Define the term Standard Enthalpy of Formation.

Back

The enthalpy change when one mole of a compound is formed from its elements under standard conditions.

Card 3

Front

What is the standard enthalpy change of combustion of 37g of 2-chlorobutane that heats 2.5dm3 of water from 20'C to 41.5'C?

Back

Preview of the front of card 3

Card 4

Front

What is the standard enthalpy change of neutralisation of 37g of 50 cm3 of 1mol dm3 HCl and 50 cm3 of 1 mol dm3 H2SO4 when the temperature of the solution rises by 16’C?

Back

Preview of the front of card 4

Card 5

Front

Given that ΔH°c of S is – 442.6 kJmol-1, ΔH°c of H2 is – 285.8 kJmol-1 and ΔH°c of H2S is – 519.1 kJmol-1, find the standard enthalpy change of formation of hydrogen sulfide.

Back

Preview of the front of card 5
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