Although atoms may be neutral, they will still be made up of negative and positive charges. Van der Waals forces are the very weak electrostatic attractions that occur between all atoms and molecules.
In any atom, the electrons could be anywhere, although the whole atom is always neutral. This means that where the dipole moment occurs changes constantly, and therefore this is known as a temporary dipole.
This temporary dipole affects the electron distribution in nearby atoms - the positive part of the atom will be attracted to the negative part of the first atom. The nearby atoms have experienced 'induced dipoles' because the dipole moment in their atom was created by the dipole moment in another atom.
The electron distribution in the original atom still changes constantly (as does its dipoles) and will therefore induce new dipoles in the atoms around it due to the attraction. These forces are called instantaneous dipole-induced dipole forces, better known as Van der Waals forces.
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