Covalent substances

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  • Created by: emews
  • Created on: 18-11-17 18:08
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  • Covalent substances
    • A covalent bond forms when two non-metal atoms share a pair of electrons.
      • The electrons involved are in the outer shells of the atoms.
      • An atom that shares one or more of its electrons will complete its outer shell.
    • Covalent bonds are strong - a lot of energy is needed to break them.
    • Atoms may form multiple covalent bonds - they share not just one pair of electrons but two or more pairs.
    • The number of covalent bonds is equal to eight minus the group number.
    • Covalently bonded substances fall into two main types:
      • simple molecules
        • Simple molecules contain only a few atoms held together by covalent bonds.
        • Properties
          • Low melting and boiling points - this is because little energy is needed to break the weak intermolecular forces.
          • Do not conduct electricity - this is because they do not have any free electrons or an overall electric charge.
      • giant covalent structures
        • Giant covalent structures contain very many atoms, each joined to adjacent atoms by covalent bonds.
        • The atoms are usually arranged into giant regular lattices - extremely strong structures because of the many bonds involved.
        • Properties
          • Very high melting points – this is because a lot of strong covalent bonds must be broken. Graphite, for example, has a melting point of more than 3,600°C.
          • Variable electrical conductivity - diamond does not conduct electricity, whereas graphite contains free electrons so it does conduct electricity. Silicon is a semi-conductor – it is midway between non-conductive and conductive.

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