Organic Synthesis

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What type of reaction do alkanes typically undergo?
Radical Substitution
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What type of reaction do alkenes typically undergo?
Electrophilic addition
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What types of reactions do alcohols typically undergo?
Nucleophilic substitution/ Dehydration/ Elimination/ Oxidation
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What type of reaction do haloalkanes typically undergo?
Nucleophilic Substitution
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What type of reaction do aldehydes typically undergo?
Oxidation
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Which two organic species are typically unreactive?
Ketones and carboxylic acids
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What conditions are needed to produce a haloalkane from an alkane?
X2 + UV light
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What conditions are needed to produce an alcohol from a haloalkane?
warm NaOH or KOH, H2O, reflux
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What is produced when an alcohol reacts with NaX, in the presence of H2SO4, at room temperature?
A haloalkane
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When heated under reflux with acidified potassium dichromate what do a) a primary alcohol and b) a secondary alcohol form?
a) a carboxylic acid b) a ketone
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How do we produce an aldehyde from a primary alcohol?
By using the distillation set up rather than reflux
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Describe the conditions needed for electrophillic addition of an alkene and name the product formed
H2, nickel catalyst, 150 degrees celsius product= a saturated hydrocarbon
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At room temperature what will be formed if you react an alkene with a) HX and b) X2
a) haloalkane b) dihaloalkane
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which two catalysts could be used to produce an alkene from an alcohol being heated?
Concentrated sulfuric acid (H2SO4) or phosphoric acid (H3PO4)
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State the conditions needed to form an alcohol from an alkene.
Steam, H3PO4 catalyst, 300 degrees celsius, 60-70 atm pressure
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What is the reaction used to test for the stength of different carbon-halogen bonds?
Formation of an alcohol from a haloalkane, using water, in the presence of AgNO3.
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What reaction is used as a test for unsaturation?
The reaction between bromine (in the form of Bromine water) and an alkene to form a dibromoalkane
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In a subsitution reaction of an alcohol with iodine why is phosphoric acid used as a catalyst when substitution reactions with alcohols and bromide use sulfuric acid?
The iodide ions would be oxidised by the acid to form I2 and so yeilds would be very poor.
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Other cards in this set

Card 2

Front

What type of reaction do alkenes typically undergo?

Back

Electrophilic addition

Card 3

Front

What types of reactions do alcohols typically undergo?

Back

Preview of the front of card 3

Card 4

Front

What type of reaction do haloalkanes typically undergo?

Back

Preview of the front of card 4

Card 5

Front

What type of reaction do aldehydes typically undergo?

Back

Preview of the front of card 5
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