mod 5 14.1 thermodynamics

Enthalpy change is the amount of heat energy taken in or given out during any physical or chemical change under constant pressure.

Standard Pressre - 100 KPa

Standard temprature - 298 K

The enthalpy change when one mokle of a compound is formed from it's elements under standard conditions all reactants and products in there standard states.

standard molar enthalpy change for the removal of and electron from a species in the gas phase to form a positive ion and an electron, both also in the gas phase.

The standard molar enthalpy change when an electron is added to an isolated atom in the gas phase.

standard molar enthalpy change which accompanies the breaking of a covalent bond in a gaseous molecule to form two free radicals, also in the gas phase.

is the standard enthalpy change which accompanies the formation of one mole of gaseous atoms.

The standard molar enthalpy change which accompanies the separation of one mole of a solid ionic lattice into gaseous ions.

Standard molar enthalpy change for the process...

X+/- (g)-----> X+/- (aq)

Standard enthalpy for the process in which one mole of an ionic solid dissolves in an amount of water large enough to ensure that the dissolved ions are well speprated and do not interact with one another.

^G must be negative or Zero for easible change.

^G = ^H - T^S

For a system at equllibrium ^G is 0

so...

^G = ^H - T^S goes to ^H - T^S