{Electrolysis - want in molten state -> from solid to molten state
high temperature = more energy}
—> the extraction method used depends upon the metal’s position in the reactivity series.
—> in principle, any metal could be extracted from its compounds using electrolysis. —> however, large amounts of electrical energy are needed to do this, so electrolysis is expensive.
—> if a metal is less reactive than carbon, it can be extracted from its compounds by heating with carbon.
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Reactivity series
{MOST reactive}
K Potassium Na Sodium Ca Calcium Mg Magnesium Al Aluminium C Carbon Zn Zinc Fe Iron Sn Tin Pb Lead Cu Copper Ag Silver Au Gold Pt Platinum
{LEAST reactive}
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Comparing electrolysis and reduction
Electrolysis
—> Key features of the method :
elements are formed at cathode & anodes
electricity is used for decomposition
—> It is more expensive than reduction because :
anodes need to be replaced
large amount of energy needed to go from solid to molten
high temperatures
electrodes need replacing
—> The metals that are extracted this way and why :
aluminium -> electrolysed
more reactive than carbon
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2
Reduction
—> Key features of the method :
high temperatures
batch process
additional substances, e.g. metals are involved in the reduction process
inert substance required
—> The metals that are extracted this way and why :
titanium can’t be electrolysed
titanium carbode forms which is brittle
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Batch process
—> a series of operations are carried out over a period of time in a separate, identifiable item or part of material
—> extraction of Ti
—> time consuming - is constantly stopped and restarted to clean etc.
—> flexibility - can change products
—> trial and error opportunities
—> more labour required - transfer of products to the next stage
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Continuous process
—> all operations occur at the same time and the material being processed is not divided into identifiable positions
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