Chemistry - Additional
These are additional chemistry notes.
- Created by: Nusrath
- Created on: 01-04-10 21:20
Atomic Structure
- The nucleus of an atom is made up of protons are neutrons.
- Protons have a positive charge, electrons have negative charge and neutrons have no charge.
- The atomic number (proton number) of an element = the number of protons in the nucleus of its atoms.
- Elements are arranged in order of their atomic numbers in the periodic table.
Arrangements of electrons in an atom
- Electrons in atoms can be represented by shells as energy levels.
- Electrons in the lowest energy level are in the shell closest to the nucleus.
- All elements in a group of the periodic table have the same number of electrons in their outer shell.
- Electrons occupy energy levels from the lowest first eg: neon with 10 electrons is 2.8.
Chemical Bonding
- Noble gases are unreactive becasue they have stable arrangements of their electrons.
- Atoms of other electrons can achieve stable electronic structures by gaining or losing electrons to form ions, or by sharing electrons to form colvalent bonds.
- Group 1 lose their single outer shell electron eg: Sodium Na (2.8.1) forms sodium ions, Na+ (2.8) ---> group 7 gains one electron to form ions eg: Chlorine Cl (2.8.7) forms chloride ions Cl- (2.8.8)
- Positive and Negative Ions attract and form ionic bonds.
Ionic Bonding
- Ionic Bonding holds oppositely charged ions together in giant structures.
- Strong electrostatic forces of attraction act in all directions.
- Each ion in the lattice is held together firmly by surrounding ions with the opposite charge.
- The Sodium Chloride structure contains equal numbers of sodium ions and chloride ions as shown by its formula NaCl.
- Both ions alternate to form a cubic lattice.
- The ratio of ions in the formula and structure nof an ionic compund depensd on the charge on the ions eg: Magnesium ions are Mg²+ and Chloride ions are Cl¯ so chloride needs 2 to make the formula balanced.---> It would make MgCl².
- The ratio would then be 1:2
Covalent Bonding
- A covalent bond is a strong bond between two non metal atoms by sharing a pair of electrons from the outer shell.
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Hydrogen and chlorine can each form one covalent bond, oxygen two bonds, nitrogen three, while carbon can form four bonds.
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Covalent bonds are strong - a lot of energy is needed to break them. Substances with covalent bonds often form molecules with low melting and boiling points, such as hydrogen and water.
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Atoms can form more than one covalent bond.
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There is a quick way to figure out how many covalent bonds an atom has.
Group 4Group 5Group 6Group 7 example carbon nitrogen oxygen chlorine number of bonds 8 - 4 = 4 8 - 5 = 3 8 - 6 = 2 8 - 7 = 1
Hydrogen forms one covalent bond. The noble gases in Group 0 do not form any!
Covalent Bonding Continued......
Double and triple Bonds:
- A molecule of oxygen (O2) consists of two oxygen atoms held together by a double bond, like this: O=O. A molecule of nitrogen (N2) has two nitrogen atoms held together by a triple bond, like this:
Dot and Cross Diagrams:
Ionic Compounds
Ionic bonds form when a metal reacts with a non-metal. Metals form positive ions; non-metals form negative ions. Ionic bonds are the electrostatic forces of attraction between oppositely charged ions.
- The oppositely charged ions are arranged in a regular pattern to form giant ionic lattices. Ionic Compounds often form crystals as a result.
Properties of Ionic Compounds:
- High Melting and Boiling Points- Ionic bonds are very strong - a lot of energy is needed to break them. So ionic compounds have high melting and boiling points.
- Conductive when liquid - Ions are charged particles, but ionic compounds can only conduct electricity if their ions are free to move. Ionic compounds do not conduct electricity when they are solid - only when dissolved in water or melted.
Covalent Compounds
Covalent bonding occurs between non metal atoms. Each bonds consists of a shared pair of electrons, and is very strong. There are two main types of covalently bonded substances: 1.) Simple Molecules and 2.) Giant Covalent Structures.
Simple Molecules:
- Contain only a few atoms held together by strong covalent bonds.
- An example of this could be Carbon Dioxide, where one atom of Carbon is bonded with two atoms of Oxygen.
Properties of simple molecular substances:
- Low Melting and Boiling Points - This is becasue the weak intermolecular forces break down easily.
- Non - Conductive - Substances with a simple molecular structure do not conduct electricity. This is because they do not have any free electrons or an overall electric charge.
Continued...(Higher Tier Only)
- Hydrogen, ammonia, methane and water are also simple molecules with covalent bonds.
- They all have very strong bonds between the atoms, but much weaker forces holding the molecules together.
- When one of these subtances melts or boils, it is these 'weak intermolecular forces' that break, not the strong covalent bonds.
- Simple molecular substances are gases, liquids or solids with low melting and boiling points.
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