Alkenes react in the cold with pure liquid bromine, or with a solution of bromine in an organic solvent like tetrachloromethane. The double bond breaks, and a bromine atom becomes attached to each carbon. The bromine loses its original red-brown colour to give a colourless liquid. In the case of the reaction with ethene, 1,2-dibromoethane is formed.
When Br2 approaches,the Br--Br bond becomes polar. A pair of electrons flow from the double bond to the slightly positive Cl and a bond is formed.
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