Reactions of benzene CH4

I've probably missed some things out / got something wrong. 

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  • BENZENE
    • Nitrobenzene
      • Phenylamine
        • Benzene diazonium ion
          • Azo dye
          • HNO2, HCl
          • Azo coupling reaction: Phenol + diazonium ion
        • HNO2, HCl
      • 100°C, Sn, conc.HCl
        • Phenylamine
          • Benzene diazonium ion
            • Azo dye
            • Azo coupling reaction: Phenol + diazonium ion
      • Reduction
      • 50°C, H2SO4, HNO3
        • Nitrobenzene
          • 100°C, Sn, conc.HCl
            • Reduction
          • Electrophilic Sunbstitution
            • Chlorobenzene
              • Phenol
              • Methylbenzene (Alkylbenzene)
                • Benzene carboxylic acid
                • Oxidation
                  • Benzene carboxylic acid
                • Reflux, KMnO4, in Alkali
                • Electrophilic substitution
                  • Methylbenzene (Alkylbenzene)
                    • Oxidation
                      • Reflux, KMnO4, in Alkali
                    • Iodomethane (Haloalkane), AlCl3, Dry
                      • Phenylethanone
                      • Bromobenzene
                        • Phenol
                      • Dark, Room temp, Dry, Halogen carrier eg. AlCl3
                      • Electrophilic Substitution
                      • Alkaline hydrolysis
                      • Heat, NaOH
                      • CH3COCl (Ethanoyl Chloride)
                      • Electrophilic Substitution
                      • N.B. NOT the same conditions!
                      • Br2, Fe catalyst, Dry
                      • Electrophilic substitution

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