analytical techniques

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  • analytical techniques
    • mass spectrometry
      • used to find Mr of a compound
      • molecular ion formed when a molecule loses an e-
        • Mass/charge value of the molecular ion peak is equal to the molecular mass of the compound
      • high resolution mass spectrometry
        • used for identifying compounds that appear to have the same Mr when they're rounded to the nearest whole number
    • infrared spectrometry
      • bonds in a molecule absorb infrared radiation at characteristic wave numbers
        • unique
      • 'fingerprinting' allows identification of a molecule by comparison of spectra
      • 1. the IR radiation is absorbed by the covalent bonds, increasing vibrational energy
        • 2. bonds between different atoms absorb different IR frequency
          • bonds in different places also absorb different frequencies
      • limitations: doesn't tell us the amount of different elements

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