Kinetics

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  • Reactions only occur when collisions take place between paerticles having SUFFICIENT energy.
  • Activation energy is the minimum energy required to start a reaction by the breaking of bonds.
  • Most collisions don't lead to a reaction because particles don't have enough energy exceeding the activation energy, and particles don't have the correct orientation. 
  • Rate of a chemical reaction - defined as the change in concentration of a substance in a given time. units: MOLDM-3S-1
  • As a reaction proceeds, the rate decreases as the concentration of reactants falls. 
  • The rate at a particular time is equal to the gradient at that time.

FACTORS AFFECTING REACTION RATE

  • Concentration - increasing the concentration increases the rate, this is because there are more particles in a given volume, so there are more frequent SUCCESSFUL collisions in a given time. 
  • Pressure - Increasing the pressure of gases increases the rate,this is because the same particles are in a smaller volume, therefore there will be more frequent successful collisions.
  • Surface area - increasing the SA of solids increases the rate, this is because breaking solids into finer powder exposes more of the particles,

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