Chemical Changes
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- Created by: arawcliffe9
- Created on: 09-03-19 16:10
Acids and Bases
pH scale 0 - 14
- lower= more acidic
- higher=more alkaline
- neutral=pH 7
- indicator is a dye that changes colour if above or below a certain pH
- acids and bases neutralise each other
- acid= h+ ions in water
- base=pH greater than 7
- alkali is base that dissolves in water form OH- ions in water
- neutralisation: acid+base=salt+water
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Titration
- Used to find out concentration + whats needed to neutarlise it
- pipette and pipette filler
- add alkali to conical flask + indicator
- funnel to fill burette with acid (known concentration)
- wear safety glasses
- fill below eye level
- record intitial volume
- use burette to add acid slowly
- until end-point (colour change)
- indicator changes colour when all alkali is neutralised
- record final volume
- to increase accuracy look for anomalous results
- first titration= rough to get approximate idea
- repeat more accurately
- calculate mean
- single indicators:
- (blue in alkalis and red in acids)
- phenolphthalein (pink in alkalis colourless in acids)
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Strong and Weak Acids
- Acids produce protons in water
- Strong acids fully ionise in water = fast rate of reaction so more reactive
- weak do not fully ionise = reversible reaction = equilibrium to the left
- pH (the measure of the conc of hydrogen ions)
- decrease of 1 on pH scale h+ ions x10
- acid strength tells you proportion of acid molecules ionised in water
- concentration= how much acid in water
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Reactions of Acids
- Metal oxides and hydroxides= bases (react with acids to form salt and water)
- if they dissolve in water=alkalis
- Acid + metal carbonate = salt + water + carbon dioxide
- insoluble salts can be mad using an insoluble base:
- warm dilute acid
- add insoluble base to acid (in excess)
- filter out excess to get salt solution
- heat solution and then leave to form crystals (crystallisation)
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Reactivity Series
- metals- how easily they loose an electron (form postive ions)
- most reactive:
- potassium - K
- sodium - Na
- lithium - Li
- calcium - Ca
- magnesium - Mg
- carbon - C (non-metal)
- zinc - Zn
- iron - Fe
- Hydrogen - H (non-metal)
- Copper - Cu
- acid + metal = salt + hydrogen
- speed of reaction indicated by bubbles given off
- reactivity= how fast reaction is
- very reactive = explosive
- metal + water = metal hydroxide + hydrogen (less reactive won't react with water)
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Seperating Metals from Metal Oxide
- Reacting with oxgen forms an oxide (example of oxidation)
- oxides are often ores that metals need to be extracted from
- metal - oxide = reduction reaction
- some can be reduced with carbon
- anything higher than carbon can not be reduced by it (have to use electrolysis)
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Redox Reactions
- if electrons are transferred = redox
- Oxidation
- Is
- Loss
- Reduction
- Is
- Gain (terms of electrons)
- REDuction + OXidation = redox reaction (happen at same time)
- displacement = example of a redox reaction
- (reactive metal "kicks out" less reactive metal)
- metal ion gains electrons
- meatl atom loses electrons
- use word symbol equations to show this
- ionic equations = useful parts of reactions
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Electrolysis
- means splitting up with electricity
- electric current passed throuh molten or dissolved ionic compound
- + ions = cathode (negative electrode) and gain electrons = reuced
- - ions = anode (positive electrode) and losse electrons = oxidised
- when loose/gain form uncharged element and then discharged from electrolyte
- molten ionic compounds can be electrolysed ions free to move + carry current
- metals being ectraced from their ores is very expensive
- need a lot of energy to melt ore and create current
- Aluminium exrtracted from ore bauxite (contains aluminium oxide)
- cryolite added to lower melting point
- molten mixture= free ions =conduct electricity
- Al3+ negative electrode + pick up +3 electrons = aluminium atoms
- O2 goes to positive elctrode -2 electrons = combine to form O2
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Electrolysis of Aqueous Solutions
- will still have hydrogen and hydroxide ions
- cathode= h+ ions and metal ions hydrogen gas produced if more reactive than hydrogen
- if less reactive a solid layer ofp pure metal produced
- at anode if OH- and halide ions (Cl- Br- I-) molecules of cholorine, bromine or iodine formed
- no halide ions= oxygen formed
- cooper sulfate (II) contains Cu2+ SO (2-, 4) H+ and OH-
- copper metal produced and coats electrode
- no halide ions so anode oxygen and water produced
- chlorine bleaches litmus paper turning it white
- hyrdogen makes a squeaky pop with lighted splint
- oxygen relights a glowing splint
- for half equations make sure elctrons are balanced
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