C2 Elements, mixtures and compounds
- Created by: chelseaboy03
- Created on: 27-01-18 10:15
Ionic Bonding
Ionic bonding occurs when atoms lose or gain electrons to form a full outer shell
Groups 1,2 and 6,7 are most likely to undergo ionic bonding as it is easier for them to gain a full outer shell
As you go down group 1 and 2 reactivity increases because as the electron is further away from the nucleus, it is easier to lose electrons
As you go down group 6 and 7 reactivity decreases as it is harder for the nucleus to attract
Ionic Compounds
Ionic compounds have a regular lattice structure that is tightly packed
They have strong electrostatic forces of attraction in all directions so:
There are high melting and boiling points
They don't conduct when solid as the ions are fixed, but when it melts it does
They can easily dissolve in water and carry a charge
Covalent Bonding
This occurs between non-metals as they share electrons to gain a full outer shell
This creates a strong covalent bond because there is a strong electrostatic attraction between the positive and negative nuclei
Simple Molecules
These are small molecules created by strong covalent bonds
The intermolecular forces are very weak so :
They have low melting and boiling points as the particles can be easily parted
They don't conduct electricity as the atoms can't move
Most of the substances are gases or liquid at room temperature
Giant Covalent Structures
They contain many strong covalent bonds
The structure is similar to giant ionic lattices, but there are no charged ions
They have high melting and boiling points but don't conduct electricity
Carbon forms many giant covalent structures because it can form up to four bonds
Diamond
Pure diamond is lustrous and colourless
4 carbon bonds form to give a strong and rigid structure
Because of the strong covalent bonds, there is a high melting and boiling point :
This makes it ideal for use in cutting tools
Diamond does not conduct electricity because there are no free electrons or ions
Graphite and Graphene
Graphite is black and opaque
Each carbon atoms form 3 covalent bonds in sheets
These sheets of carbon can slide over each other - which makes it good as a lubricating material
Graphite also has a high melting and boiling point and it conducts electricity due to the delocalised electrons
Graphene is a single sheet of graphite, Graphene is very strong and light and is better at conducting electricity because the delocalised electrons are completely free
Fullerenes
Fullerenes are also made of carbon and are shaped as hollow tubes or balls
Different fullerenes contain different numbers of carbon
Like graphite, the fullerenes are arranged in rings and also have delocalised electrons to conduct electricity
They have pretty high melting and boiling points but are not as high as diamond or graphite
Nanoparticles
Nanoparticles are about 1-100nanometres across - fullerenes are nanoparticles
Nanoparticles have different properties from the bulk material
They also have a high surface area to volume ratio which gives them different properties to larger particles
Uses:
Because of the high SA:V ratio they make good catalysts
In cosmetics, they are used as they don't leave white marks on the skin
They can be used to reduce friction
Also, they can be used in sports equipment to make the plastic stronger and more durable without adding as much mass
Polymers
Polymers are long chains of monomers
These are created using polymerisation - this normally needs a high temperature and a catalyst
Strong covalent bonds hold the atoms in the chains
If the plastic is made from weak intermolecular forces then the chains can slide over each other -this will cause a low melting point - LDPE
If the plastic has stronger bonds there is a higher melting point and it is more rigid - HDPE
Metals
Metals are in a strong regular structure with delocalised electrons
Strong metallic bonds are between delocalised electrons and positive ions
This causes a high melting and boiling point
They are also:
Malleable, strong, good conductors, and hard to break
They react with oxygen to form metal oxides and can be used in alloys for strong alloys
Purity
In chemistry, a substance is pure if it only contains a single element or compound
If it has more than one compound or element it is a mixture
To test for purity you can measure the boiling point and compare it to the expected result
If it is impure the boiling point will be higher or lower than the expected result
Distillation
Simple distillation is used to separate out a liquid from a solution
You must use solutions with very different boiling points otherwise you need fractional distillation
Fractional distillation separates out a mixture of liquids due to their boiling point
The different liquids are then condensed and collected
Filtration and Crystilisation
Filtration is used to separate an insoluble solid from a liquid
The liquid runs through the filter paper but the solid is left behind
Crystallisation separate a soluble solid from a solution
You place the solution in an evaporating dish and heat it until crystals form
You then leave it to cool and filter the crystals
Chromatography
Mobile - where molecules can move, liquid or gas
Stationary - where molecules can't move, solid
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