Chemistry Unit 1

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  • C1
    • using carbon fuels
      • choosing fuels
        • amount of fossil fuels being burnt is increasing because  populations increasing
        • a fuel is chosen because of its key features: energy value, toxicity, cost, storage, pollution caused and ease of use
        • governments are becoming concerned because CO2 emissions are increasing when fossil fuels are being burnt
      • combustion
        • complete combustion occurs when a fuel burns plenty of oxygen
        • balanced equation for incomplete combustion:   2CH4 + 3O2 --> 2CO + 4H2O       OR   CH4 + O2 --> C + 2H2O
        • balanced equation for complete combustion:     CH4 + 2O2 --> CO2 +2H2O
        • word equations for combustion are:               fuel + oxygen --> carbon monoxide + water OR      fuel + oxygen --> carbon + water
        • toxic gas (carbon monoxide) and soot (carbon) are made during incomplete combustion
    • design polymers
      • disposing of polymers
        • recycling is difficult
        • scientists are discovering new polymers that dissolve and are biogradeable polymers
        • research into new polymers is important as there are environmental and economic issues within the use of existing polymers
        • disposal by burning makes toxic gases and wastes crude oil
        • wasting land that could be used valuble for other purposes
      • breathable polymers
        • poly eurathane membrane it too fragile on its own so its laminated onto nylon to make a stronger fabric
        • GORE-TEX(r) material is waterproof and yet breathable, has all properties of nylon
        • nylon is tough, lightweight, keeps out water and keeps UV out but does not let water through
    • making crude oil useful
      • problems in extracting crude oil
        • demand of oil is very high, there is conflict between needs for making petrochemicals for fuels
        • transportation can cause oil slicks, damaging wildlife
        • may be political problems relating to the extraction of crude oil
      • fossil fuels
        • there are specific difficulties associated with the finite nature of crude oil and finding replacement
        • non-renewable as they are being made up faster than they are being formed
        • finite resources as they are no longer being made or they are but very slowly
      • fractional distillation
        • crude oil can be separated because the hydrocarbons in fractions have different sized molecules
        • high boiling point like bitumen go at the bottom of the fractional column, where low boiling points like LPG go at the top
        • crude oil is a mixture of many types of oil, which are all hydrocarbons
        • crude oil is heated at the bottom of a fractioning column
      • cracking
        • process turning large alkane into smaller alkaneand alkene molecules
        • helps oil manufactures match supply with demand
    • cooking food additives
      • baking powder
        • word equation for decomposition of sodium hydrocarbon ate:      sodium hydrocarbonate --> sodium carbonate + carbon dioxide + water
        • when it is heated it breaks down(decomposes) to give carbon dioxide
        • symbol equation for decomposition of sodium hydrocarbon ate:        2NaHCO3 --> Na2CO3 + CO2 +H2O
        • sodium hydrocarbonate
      • emulsifiers
        • are molecules that have amwathr loving part and an oil loving part
        • water end (headl) of emulsifying molecule is hydrophilic
        • oil end(tail) of emulsifying molecule is hydrophobic
        • help keep oil and water from separating
      • proteins and carbohydrates
        • a potato is a carbohydrate, which is easier to digest when cooked as starch swells up and spreads out; cell wall ruptures
        • texture of egg/meat changes when cooked because shapes of protein change permanently
        • protein molecules in eggs and eat permanently change shape when cooked - denaturing
    • clean air
      • the atmosphere
        • overtime,  organisms that could photosynthisise evolved and converted carbon dioxide and water into oxygen
        • gases come through centre of earth by volcanoes- degassing
        • gases escaping from the interior earth formed the original atmosphere
      • pollution control
        • sulfur dioxide i a pollutant that can cause difficulty for people with asthma
        • a car fitted with a catalytic converter changes carbon monoxide into carbon dioxide
        • in a catalyst converter, a reaction takes place on the surface of the catalyst. the gases formed are in natural air: nitrogen and carbo dioxide
        • important to control as of the effects on health, natural environment and built environment
      • what is in air?
        • over last few centuries, percentages of carbon dioxide has grown because of increased population and deforestation
        • 71% nitrogen 21% oxygen 0,035% carbon dioxide
        • there is a balance between the carbon cycle that use up and both make carbon dioxide and oxygen
    • paints & pigments
      • phosphorescent pigments
        • much safer than older alternative radioactive paints
        • they glow in the dark because they absorb and store energy and release it as light overtime
      • paint drying
        • oil paints dry as solvent evaporates and is oxidised
        • emulsion paints are waterbed that dry when solvent evaporates
        • most paints dry as they are applied with a thin layer, solvent evaporates
      • colloids
        • components will not seperate as particles are separated and dispersed through mixture and are small
        • paint is a colloid where particles are mixed and dispersed with particles of a liquid
      • thermocrhomic pigments
        • change colour at different tempeatures
        • can be added to acrylic paints to make even more colour changes
    • smells
      • perfume properties
        • must be non-toxic
        • must evaporate easily
        • must not react with water
        • not to irritate skin
        • must be insoluble in water
      • esters
        • alcohol + acid --> ester + water
        • used to make perfume
        • made by : adding acid to alcohol, condenser stops gas from escaping to cool down again, so can react more and go on for loner
        • alcohol reacts with acids to make ester and water
      • solutions
        • esters can be used as solvents
        • is a mixture of solvent and solute, doesn't separate out
    • making polymers
      • polymerisation
        • polymers have long chains
        • addition polymerisation needs a high pressure and a catalyst
        • involves the reaction of many unsaturated alkenes ( monomer molecules)
        • addition polymerisation reaction has a long chain, caused the double bonds to break and from new bonds
      • hydrocarbons
        • alkanes have a single bond: CnH2n+2
        • a saturated compounds only single bonds
        • made  up of ONLY hydrogen and carbon atoms
        • unsaturated compound has at leat one double covalent bond
        • bromine is used to test for alkene. when orange bromine is added , alkene decolourises the bromine to be colourless
        • alkenes have a double bond : CnH2n
  • combustion
    • complete combustion occurs when a fuel burns plenty of oxygen
    • balanced equation for incomplete combustion:   2CH4 + 3O2 --> 2CO + 4H2O       OR   CH4 + O2 --> C + 2H2O
    • balanced equation for complete combustion:     CH4 + 2O2 --> CO2 +2H2O
    • word equations for combustion are:               fuel + oxygen --> carbon monoxide + water OR      fuel + oxygen --> carbon + water
    • toxic gas (carbon monoxide) and soot (carbon) are made during incomplete combustion

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