Thermodynamics

Quiz for unit 5 aqa chemistry A2

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What is enthalpy of formation?
Enthalpy change when one mole of a compound is formed from its elements. Compound and elements in standard states.
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What state are ions in for 1st ionisation enthalpy?
Gaseous
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What is bond dissociation enthalpy?
Enthalpy change when one mold of gaseous covalent bonds is broken homolytically, forming free radicals
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What is: 'the enthalpy change when one mole of free gaseous ions is added to an excess of water'?
Enthalpy of hydration
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What is bond breaking?
Endothermic
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Why is second electron affinity endothermic?
Repulsion between oppositely charged ions must be overcome
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How can you calculate enthalpy of solution?
enthalpy of lattice dissociation + (sum of hydration enthalpies)
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How can you calculate enthalpy change of a reaction?
(sum of bonds broken) - (sum of bonds formed)
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When is a lattice soluble?
When enthalpy of solution is exothermic
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What is a spontaneous reaction?
A process that will proceed without any external influence
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What is entropy?
A measure of the ways in which particles can be rearranged, and energy measured.
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How do you calculate entropy?
(sum of entropy of products) - (sum of entropy of reactants)
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What is the unit of entropy?
JK-1mol-1
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How do you calculate gibbs free energy?
enthalpy change - (T*entropy change)
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When is a reaction spontaneous?
When GFE is less than or equal to 0
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Other cards in this set

Card 2

Front

What state are ions in for 1st ionisation enthalpy?

Back

Gaseous

Card 3

Front

What is bond dissociation enthalpy?

Back

Preview of the front of card 3

Card 4

Front

What is: 'the enthalpy change when one mole of free gaseous ions is added to an excess of water'?

Back

Preview of the front of card 4

Card 5

Front

What is bond breaking?

Back

Preview of the front of card 5
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