Synthetic Routes 0.0 / 5 ? ChemistrySynthetic RoutesA2/A-levelAQA Created by: AbbieBroomfieldCreated on: 12-01-16 15:33 Alkane to Haloalkane Reagents: Chlorine, Conditions: UV Light, Equation: CH4 +Cl2 --> CH3Cl + HCl FREE RADICAL SUBSTITION 1 of 9 Haloalkane to Alcohol Reagents: aqueous NaOH , Conditions: warm/reflux , Equation: R-Cl + NaOH --> R-OH + NaCl NUCLEOPHILLIC SUBSTITUTION 2 of 9 Haloalkane to alkene Reagents: KOH , Conditions:ethanol/heat under reflux , Equation: CH2CH2Cl + KOH --> CH2=CH2 + KCL + H2O ELIMINATION 3 of 9 Haloalkane to Nitrile Reagents: KCN , Conditions: Heat and Reflux , Equation: R-Cl + KCN --> R-CN + KCL NUCLEOPHILLIC SUBSTISTION 4 of 9 Haloalkane to Primary Amine Reagents: excess ammonia , Conditions: heat , Equation: R-Cl + 2NH3 --> R-NH2 + NH4Cl NUCLEOPHILLIC SUBSTITUTION 5 of 9 Primary amine to Secondary amine Reagents: chloroalkane , Conditions: warm, Equation: R1-NH2 + R2-Cl --> R1R2NH + HCl NUCLEOPHILLIC SUBSTITUTION 6 of 9 Secondary amine to tertiary amine Reagents: chloroalkane , Conditions: warm, Equation: R1R2NH +R3-Cl --> R1R2R3N + HCl NUCLEOPHILLIC SUBSTITUTION 7 of 9 tertiary amine to quatenary ammonium salt Reagents: chloroalkane , Conditions: warm, Equation: R1R2R3N + R4-Cl --> R1R2R3R4N+Cl- NUCLEOPHILLIC SUBSTITUTION 8 of 9 Alkene to Alkane Reagents: Hydrogen/ Ni catalyst , Conditions: 150 degrees, 2atm , Equation: CH2=CH2 + H2 --> CH3CH3 9 of 9
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