Reactions to know - A level CHemistry OCR A A2

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Carboxylic acid to an Ester - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: Alcohol Conditions: Heat Catalyst: H2SO4(Sulphuric acid) Type/Mechanism: Esterification
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Ester to Carboxylic acid - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: Water Conditions: Heat under reflux Catalyst: HCL(Hydrochloric acid aqueous) Type/Mechanism: Acid Hydrolysis
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Ester to Alchohol - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Either Reactants: Water Conditions: Heat under reflux Catalyst: HCL(aq) Type/Mechanism: Acid Hydrolysis or Reactants: NaOH Conditions: Heat under reflux Type/Mechanism: Alkaline Hydrolysis(saponification)
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Carboxylic acid to Acyl Chloride - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: SOCL2(thionyl chloride) Note: HCl and SO2 produced as by-prodcts
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Acyl Chloride to Carboxylic acid - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: Water Type/Mechanism: Nucleophilic Addition-Elimination
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Aldehyde to Carboxylic acid - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: [O] Conditions: Heat under reflux Catalyst: K2Cr2O7/H+(Acidified Potassium dichromate) Type/Mechanism: Oxidation
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Aldehyde to Hydroxynitrile(Cyanohydrin) - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: KCN Catalyst: H2SO4(Sulphuric acid) Type/Mechanism: Reduction/Nucleophilic Addition Note: Ethanol solution used
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Ketone to Hydroxynitrile(Cyanohydrin) - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: KCN Catalyst: H2SO4(Sulphuric acid) Type/Mechanism: Reduction/Nucleophilic Addition Note: Ethanol solution used
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Ketone to Alcohol - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: H+ Catalyst: NaBH4(Sodium Borohydride) Type/Mechanism: Nucleophilic addition
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Aldehyde to Alcohol - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: H+ Catalyst: NaBH4(Sodium Borohydride) Type/Mechanism: Nucleophilic addition
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Alcohol to Aldehyde - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: [O] Conditions: Distilation Catalyst: K2Cr2O7/H+(Acidified Potassium dichromate) Type/Mechanism: Oxidation
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Alcohol to Ketone - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: [O] Conditions: Heat under reflux Catalyst: K2Cr2O7/H+(Acidified Potassium dichromate) Type/Mechanism: Oxidation
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Alkane to Haloalkane - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: Cl2/Br2 Conditions: UV light Type/Mechanism: Free Radical Substitution
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Alkene to Haloalkane - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: HCl/HBr Type/Mechanism: Electrophilic Addition
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Alkene to Dihaloalkane - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: Cl2/Br2 Type/Mechanism: Electrophilic Addition
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Haloalkane to Alchohol - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: NaOH(aq) Conditions: Heat under reflux Type/Mechanism: Nucleophilic Substitution
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Alchohol to Alkene - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: H2SO4(Sulphuric acid Conc.) Conditions: Heat Type/Mechanism: Elimenation/Dehydration Note: Major(trans) and Minor(cis) products
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Alkene to Alcohol - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
1. Add H2SO4 (SUlphuric acid) Nucleophilic Addition 2. Add warm water Hydrolysis
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Haloalkane to Nitrile - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: KCN in ethanol solution Conditions: Heat under reflux Type/Mechanism: Nucleophilic Substitution
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Nitrile to Primary Amine - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: 2LiAlH4 Type/Mechanism: Reduction
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Primary Amine to Secondary Amine - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Add Haloalkane and Neutralise the salt with NaOH
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Acyl Chloride to Primary Amide - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: 2NH3 (Ammonia) Conditions: Room Temperature Type/Mechanism: Nucleophilic Addition-Elimination Note: Ammonium Chloride is also formed
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Acyl Chloride to Secondary Amide - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: 2Primary Amine Note: Ammonium Chloride salt is also formed
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Primary Amine to Secondary Amide - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: Acyl Chloride Note: Ammonium Chloride is also formed
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Benzene to Benze with Alkly chain - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: Haloalkane Catalyst: AlCl3/FeBr3 Type/Mechanism: Friedel-Crafts Alkylation/Electrophilic Substitution
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Benzene to Halobenzene - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: Halogen Catalyst: AlCl3/FeBr3 Type/Mechanism: Electrophilic Substitution
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Benzene to PhenylKetone - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: Acyl Chloride Catalyst: AlCl3/FeBr3 Type/Mechanism: Electrophilic Substitution
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Benzene to Nitrobenzene - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Preceding reaction: HNO3 + H2SO4 -> NO2+ + HSO4- + H2O Reactants: NO2+ Conditions: 50 degrees Catalyst: H2SO4(Sulphuric acid) Type/Mechanism: Nitration/Electrophilic Addition
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Nitrobenzene to Phenylamine - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
1. Sn and HCl 2. NaOH to neutralise the salt formed
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Phenol to Tribromophenol - Reactants - Conditions - Catalyst (if required) - Type/Mechanism
Reactants: 3Br2
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Other cards in this set

Card 2

Front

Ester to Carboxylic acid - Reactants - Conditions - Catalyst (if required) - Type/Mechanism

Back

Reactants: Water Conditions: Heat under reflux Catalyst: HCL(Hydrochloric acid aqueous) Type/Mechanism: Acid Hydrolysis

Card 3

Front

Ester to Alchohol - Reactants - Conditions - Catalyst (if required) - Type/Mechanism

Back

Preview of the front of card 3

Card 4

Front

Carboxylic acid to Acyl Chloride - Reactants - Conditions - Catalyst (if required) - Type/Mechanism

Back

Preview of the front of card 4

Card 5

Front

Acyl Chloride to Carboxylic acid - Reactants - Conditions - Catalyst (if required) - Type/Mechanism

Back

Preview of the front of card 5
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