Organic Synthesis (Flashcards/Quiz) All the reactions that need to be learned. 4.5 / 5 based on 4 ratings ? ChemistryReactionsA2/A-levelAQA Created by: KynaCreated on: 28-11-12 11:58 Haloalkane --> Secondary/Tertiary Amines and Quaternary Salts Ammonia, heat. 1 of 21 Haloalkane --> Primary Amine Ammonia, heat 2 of 21 Haloalkane --> Nitrile CN- , ethanol, reflux 3 of 21 Haloalkane --> Alcohol NaOH, reflux 4 of 21 Haloalkane --> Alkene NaOH, ethanol, reflux 5 of 21 Nitrile --> Primary Amine LiAlH4 in diethyl ether/dilute acid 6 of 21 Alkene --> Haloalkane HBr, 20oC 7 of 21 Alkene --> Dibromoalkane Br2, 20oC 8 of 21 Alkane --> Haloalkane Cl2, U.V. light 9 of 21 Alcohol --> Alkene conc H2SO4, reflux 10 of 21 Alkene --> Alcohol H3PO4 catalyst, steam, 300oC, 60-70atm OR H20, H2SO4 catalyst 11 of 21 Alcohol --> Aldehyde/Ketone K2Cr2O7, H2SO4, heat and reflux (excludes tertiary alcohols) 12 of 21 Aldehyde/Ketone --> Alcohol NaBH4 in H2O with methanol 13 of 21 Aldehyde/Ketone --> Hydroxynitrile CN-, H+, 20oC 14 of 21 Aldehyde --> Carboxylic Acid K2Cr2O7/H2SO4, reflux 15 of 21 Carboxylic Acid --> Ester Alcohol, conc. H+ catalyst, reflux 16 of 21 Ester --> Carboxylic Acid Dilute H+ catalyst, H2o, reflux 17 of 21 Acyl chloride --> Carboxylic Acid H20, 20oC 18 of 21 Acyl Chloride --> Ester Ethanol, 20oC 19 of 21 Acyl Chloride --> Primary Amide NH3, 20oC 20 of 21 Acyl Chloride --> N-Substituted Amide Amine, 20oC 21 of 21
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