Organic Synthesis 0.0 / 5 ? ChemistryOrganic SynthesisReactionsA2/A-levelAQA Created by: AJAJINGLECreated on: 25-12-17 20:00 Alkene ---> Polyalkene High pressure, Catalyst 1 of 23 Alkene ---> Halogenoalkane HBr or HCl, Room Temp (Electrophilic Addition) 2 of 23 Ethene ---> Ethanol Reaction with Steam, Phosphoric acid catalyst 3 of 23 Alkane ---> Halogenoalkane Br2 or Cl2, UV light (Free Radical Substitution) 4 of 23 Halogenoalkane ---> Alcohol Aqueous NaOH, (Nucleophilic Substitution) 5 of 23 Halogenoalkane ---> Nitrile Ethanolic KCN, Heat, Reflux (Nucleophilic Substitution) 6 of 23 Halogenoalkane ---> Primary Amine Alcoholic NH3, Heat under pressure (Nucleophilic Substitution) 7 of 23 Halogenoalkane ---> Alkene Alcoholic KOH, Heat under Reflux (Elimination) 8 of 23 Nitrile ---> Primary Amine LiAlH4 in Ether (Reduction) 9 of 23 Primary Amine ---> Secondary/Tertiary/Quaternary Amine Halogenoalkane (Nucleophilic Substitution) 10 of 23 Primary Amine ---> Secondary Amide Acyl Chloride, Room Temp (Nucleophilic Addition/Elimination) 11 of 23 Acyl Chloride/Acid Anhydride ---> Primary Amide NH3, Room Temp (Nucleophilic Addition/Elimination) 12 of 23 Acyl Chloride/Acid Anhydride ---> Secondary Amide Primary Amine, Room Temp (Nucleophilic Addition/Elimination) 13 of 23 Acyl Chloride/Acid Anhydride ---> Ester Alcohol, Room Temp (Nucleophilic Addition/Elimination) 14 of 23 Acyl Chloride/Acid Anhydride ---> Carboxylic Acid Water, Room Temp (Nucleophilic Addition/Elimination) 15 of 23 Carboxylic Acid ---> Ester Alcohol + H2SO4, Heat (Esterification) 16 of 23 Alcohol ---> Ester Carboxylic Acid + H2SO4, Heat (Esterification) 17 of 23 Alcohol ---> Alkene Concentrated H2SO4 (Elimination/Dehydration) 18 of 23 Primary Alcohol ---> Aldehyde Dilute Sulphuric Acid, Less Potassium Dichromate than needed for full oxidation, Gentle heating, Distillation (Partial Oxidation) 19 of 23 Secondary Alcohol ---> Ketone Dilute Sulphuric Acid, Potassium Dichromate (Oxidation) 20 of 23 Primary Alcohol ---> Carboxylic Acid Concentrated Sulphuric Acid, Excess Potassium Dichromate, Gentle Heat under Reflux (Full Oxidation) 21 of 23 Aldehyde/Ketone ---> Alcohol H2, Nickel Catalyst (Reduction) 22 of 23 Aldehyde/Ketone ---> Hydroxynitrile NaCN + H2SO4 (Nucleophilic Addition) 23 of 23
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