Ionisation Energies and Periodicity

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  • Created by: DavidW001
  • Created on: 01-05-19 15:20
What Experimental Evidence is there for Electron Shells?
Ionisation energy data (jumps) and emission Spectra
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What is the Standard equation for First ionisation energy?
X(g)─>X+(g) +e-
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Trend In ionisation energy down group?
Decreases
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Trend In ionisation energy across period?
Increases
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Examples of anomalous ionisation energy
Lead (Pb) has a higher I.E. than Tin which is directly above it.
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What is an S-Block Element?
An element with its outermost electron in a an s subshell
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Which groups in the periodic table are p-block elements?
Groups 3-8
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Which groups in the periodic table are d-block elements?
Elements Scandium to Zinc in period 4 and Ytrrium to Cadmium in period 5.
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Types of Atomic Radius
Covalent radii, Van der Waals radii and Metallic radii
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Trend in Atomic Radius across a period
Decreases: Nuclear Charge outweighs increased shielding.
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Electron configuration of Phosphorus? 15
1s2, 2s2, 2p6, 3s2, 3p3
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Electron Configuration of Potassium? 19
1s2, 2s2, 2p6, 3s2, 3p6, 4s1
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Electron Configuration of Chromium? 24
1s2, 2s2, 2p6, 3s2, 3p6, 3d5, 4s1
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Quantum shell definition?
A quantum shell defines the energy level of an electron.
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Hund's rule?
Electrons will occupy the orbitals singly before pairing up.
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Pauli Exclusion Principle?
2 electrons cannot occupy the same orbital unless they have opposite spin.
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Electron configuration of Copper? 29
1s2, 2s2, 2p6, 3s2, 3p6, 3d10, 4s1
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Trend in atomic radius down a group?
Increases
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Aufbau Principle?
Builds up energy levels
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A covalent bond is?
The strong electrostatic attraction between two positive nuclei and the shared pair of electrons between them.
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Dative Covalent Bond
When an orbital with a lone pair of electrons in one atoms overlaps with a vacant orbital in another atom.
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Larger the Bond Length
Weaker the bond
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Other cards in this set

Card 2

Front

What is the Standard equation for First ionisation energy?

Back

X(g)─>X+(g) +e-

Card 3

Front

Trend In ionisation energy down group?

Back

Preview of the front of card 3

Card 4

Front

Trend In ionisation energy across period?

Back

Preview of the front of card 4

Card 5

Front

Examples of anomalous ionisation energy

Back

Preview of the front of card 5
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