Investigation into how the rate of a reaction changes with temperature

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Why is the rate of reaction equal to 1/time?
As rate = change in concentration/time, but the change in concentration is constant over all temperatures (measured as degree of cloudiness), so change in conc. = 1.
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Why does a small temperature change result in a large increase in the rate of reaction?
An increase in temperature leads to a large increase in the number of atoms/molecules with energy greater than or equal to Ea. So, there are many more successful collisions between molecules.
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How can the results be used to calculate activation energy?
Rearrange the Arrhenius equation to lnK = -Ea/R x 1/T + lnA. Plot a graph of y = lnK, x = 1/t, and gradient = -Ea/R. So Ea = -gradient x R. The gradient should always be -ve!
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3 things to remember for using a graph to calculate rate/Ea
1) Use a straight line of best fit (don't extrapolate). 2) Use all or most of the graph paper. 3) Use points far apart on the graph to calculate the gradient.
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What can lnK be replaced by on a graph?
ln(rate) as k is proportional to the rate of reaction.
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Other cards in this set

Card 2

Front

Why does a small temperature change result in a large increase in the rate of reaction?

Back

An increase in temperature leads to a large increase in the number of atoms/molecules with energy greater than or equal to Ea. So, there are many more successful collisions between molecules.

Card 3

Front

How can the results be used to calculate activation energy?

Back

Preview of the front of card 3

Card 4

Front

3 things to remember for using a graph to calculate rate/Ea

Back

Preview of the front of card 4

Card 5

Front

What can lnK be replaced by on a graph?

Back

Preview of the front of card 5

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