AS Organic Reactions

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1. Halogenoalkane to amine

  • dilute NH3, heat under reflux, r.t. or heat in sealed tube
  • conc. NH3 in ethanol, heat under reflux, r.t or heat in sealed tube
  • conc. NH3 in alkali, heat under reflux, r.t or heat in sealed tube
  • conc. NH3, heat under reflux, r.t. or heat in sealed tube
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2. Alcohol to halogenoalkane

  • PCl5, 20-30 atm
  • PCl5, heat under reflux
  • PCl5, r.t.
  • PCl5,170 degrees

3. Alkene to Alkane

  • H2, raney Ni cat. , 350 degrees, 20-30 atm
  • H2, raney Ni cat. , 350 degrees
  • H2, raney Ni cat. , 140 degrees
  • H2, raney Ni cat. , 140 degrees, 20-30 atm

4. Alkene to Polymer

  • Organic Peroxide Initiator, 1500-2000 atm
  • Phosphoric acid catalyst, 1500-2000 atm
  • Phosphoric acid catalyst, 3000 atm
  • Organic Peroxide Initiator, 3000 atm

5. Conditions and reagents from alkene to halogenoalkane

  • HX (conc or gas), 350 degrees and 20-30 atm
  • HX (conc. or gas) , r.t.p
  • HX (conc. or gas), 350 degrees
  • X2, UV light

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