3.4.4 Nomenclature and Isomerism in Organic Chemistry

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  • Created by: Jade
  • Created on: 11-05-13 17:50
Stereoisomer
isomeric molecules that have the same molecular formula and sequence of bonded atoms (constitution), but that differ only in the three-dimensional orientations of their atoms in space.
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Geometrical Isomer
Two stereoisomers have the same chemical formula but the bonds are arranged differently around the C=C double bond.
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Optical Stereoisomerism
Occurs when there are 4 differnt atoms or groups attached to 1 carbon atom. It is therefore assymetric and has a chrial centre.
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Chiral Centre
Is often marked in a chemical formula by an asterisk. When a molecule has a chiral centre, it has 2 isomers which are mirror images of one another, but you cannot superimpose one molecule onto the other.
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Enantiomers
This is what 2 optical isomers are called. Enantiomers have exactly the same physical properties except for the fact that they rotate plane polarized light in opposite directions.
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Dextro-enantiomer and Laevo-enantiomer
dextro will rotate the light clockwise. Laevo will rotate the light anticlockwise.
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Racemic Mixture
A mixture containing equal quantities of two enantiomers.
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Other cards in this set

Card 2

Front

Geometrical Isomer

Back

Two stereoisomers have the same chemical formula but the bonds are arranged differently around the C=C double bond.

Card 3

Front

Optical Stereoisomerism

Back

Preview of the front of card 3

Card 4

Front

Chiral Centre

Back

Preview of the front of card 4

Card 5

Front

Enantiomers

Back

Preview of the front of card 5
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