Ionic Bonding

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Ions are electrically charged particles formed when atoms lose or gain electrons. They have the same electronic structures as noble gases.

Metal atoms form positive ions, while non-metal atoms form negative ions. The strong electrostatic forces of attraction between oppositely charged ions are called ionic bonds.

Ions

How ions form

Ions are electrically charged particles formed when atoms lose or gain electrons. This loss or gain leaves a complete highest energy level, so the electronic structure of an ion is the same as that of a noble gas - such as a helium, neon or argon.

Metal atoms and non-metal atoms go in opposite directions when they ionise:

  • Metal atoms lose the electron, or electrons, in their highest energy level and become positively charged ions
  • Non-metal atoms gain an electron, or electrons, from another atom tobecome negatively charged ions

(http://www.bbc.co.uk/staticarchive/d58bed572cd93c4014cac54e4ee121c9d496cb70.gif)

Positively charged sodium and aluminium ions

(http://www.bbc.co.uk/staticarchive/5ff03eaadbd779a508b72fef866d8aebcebde94d.gif)

Negatively charged oxide and chloride ions

How many charges?

There is a quick way to work out what the charge on an ion should be:

  • The number of charges on an ion formed by a metal is equal to the group number of the metal
  • The number of charges on an ion formed by a non-metal is equal to the group number minus eight
  • Hydrogen forms H+ ions.
  • Note 1: carbon and silicon in Group 4 usually form covalent bonds by sharing electrons.

    Note 2: the elements in Group 0 do not react with other elements to form ions.

Representing positive ions

You need to be able to show the electronic structure of some common metal ions, using diagrams like these:

Lithium, Li

Diagrams of a lithium atom (2,1) with two electrons in its inner shell and one electron in its highest energy level, and a lithium ion (2)+ with two electrons in its highest energy level (http://www.bbc.co.uk/staticarchive/66e0e9ee0d7ec51db3b4d1dfbdedee5f55af7008.gif)

Lithium is in Group 1. It has one electron in its highest energy level. When this electron is lost, a lithium ion Li+ is formed.

Sodium, Na

Diagrams of a sodium atom (2,8,1) and a sodium ion (2,8)+ (http://www.bbc.co.uk/staticarchive/4ede6ede170a3c7104ed53c44ded45abc428e1b0.gif)

Sodium is also in Group 1. It has one electron in its highest energy level. When this electron is lost, a sodium ion Na+ is formed.

Structure of a neon atom. A black dot represents the nucleus. The small circle around this has two red dots on it, representing the first energy level with two electrons. A larger outer circle has eight red dots on it, representing the second energy level with eight electrons (http://www.bbc.co.uk/staticarchive/d74da1a5c4105e9e1d92e45aaf2d2c9c807db94d.gif)

Neon atom

Note that a sodium ion has the same electronic structure as a neon atom (Ne).

But be careful - a sodium ion is not a neon atom. This is because the nucleus of a sodium ion is the nucleus of a sodium atom and has 11 protons - but the nucleus of a neon atom has only 10.

Magnesium, Mg

Diagrams of a magnesium atom (2,8,8,2) and a magnesium ion (2,8)2+ (http://www.bbc.co.uk/staticarchive/2f2526c6c339551e2023b7dca3c7673143e40412.gif)

Magnesium is in Group 2. It has two electrons in its highest energy level. When these electrons are lost, a magnesium ion Mg2+ is formed.

A magnesium ion has the same electronic structure as a neon atom (Ne).

Calcium, Ca

Diagrams of a calcium atom (2,8,8,2) and a calcium ion (2,8,8)2+ (http://www.bbc.co.uk/staticarchive/873733ccd0c3f7c245676f0bd0cae10f85c838b6.gif)

Calcium is also in Group 2. It has two electrons in its highest energy level. When these electrons are lost, a calcium ion Ca2+ is formed.

A calcium ion has the same electronic structure as an argon…

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