Electrophilic addition in alkenes
- Created by: Bree-Ffionn
- Created on: 11-09-19 15:27
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- Alkenes are more reactive than alkanes.
- This is due to the C=C double bond.
- Mean bond enthalpy is +347 kj mol
- The double bond is an area of high electrin density so electrophiles such as Br2 and Hbr are attracted to it.
- In alkenes, the bond breaks and a small molecule is added across the two carbon atoms.
- Halogenation is an addition reaction in which a halogen is added across the C=C bond.
- Adding bromine water to an alkene will form a haloalkene and the bromine water will decolourise.
- The test for identifying an alkene is ;
- CH2CH2 =Br2 -> BrCH2Br
- Haloalkanes can be formed by an addition reaction between a hydrogen halide such as HBr and an alkene.
- Hydrogen halides like HCL, HBr and Hl are gases at room temperature so they are bubbled trough the alkene to cause a reaction.
- CH2CH2 + HBr -> CH3CH2Br
- Hydration is an addition reaction between an alkene and steam
- The alkene must be in gaseous form for the reaction to occur.
- The temperature must be high, around 300 degree celcius, as must be the pressure about 65 atm.
- Phosphoric acid acts as the catalyst
- CH2CH2 + H20 -> CH3CH3OH
- Alkenes react with concentrated sulfruic acid under cold conditions to…
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