Born-Haber Cycles

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Definitions

  • Enthalpy of formation: the enthalpy change when one mole of a compound is formed from its constituent elements under standard conditions, all reactants and products in their standard states
  • Enthalpy of combustion: the enthalpy change when one mole of substance is completely burnt in oxygen
  • Enthalpy of atomisation: the enthalpy change that accompanies the formation of one mole of gaseous atoms from the element in its standard state under standard conditions
  • First ionisation energy: the enthalpy change when one mole of gaseous atoms is converted into one mole of gaseous ions each with a single positive charge
  • Second ionisation energy: the enthalpy change when one mole of gaseous ions each with a single positive charge is converted into one mole of gaseous ions each with a double positive charge
  • First electron affinity: the enthalpy change when one mole of gaseous atoms is converted into one mole of gaseous ions

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