The Halogens

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The Halogens

  • They are electronegative elements.
  • They have a typical oxidation number of -1.
  • They are usually the oxidising agents in a reaction as they receive electrons becoming reduced.
  • The tendency to form anions decreases down the group.
  • Fluorine is the most electronegative element.
  • The melting point increases down the group from Fluorine to Iodine due to the increasing intermolecular forces holding the diatomic elements together
  • This increase is due to the increasing number of electrons in the molecules contributing to the induced dipole-induced dipole intermolecular force. 
  • Halogen + Metal --> Metal Halide
  • Reactivity decreases down the group from Fluroine to Iodine.
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Test for halide ions

This test will allow you to identify whether a halide ion is a Chloride, Bromide or Iodide ion.

  • Add Silver Nitrate 
  • The Silver Halide is then precipitated 
  • This is because Silver halide are insoluble in water

The results look like this:

  • Silver Chloride = White ppt
  • Silver Bromide = Cream ppt
  • Silver Iodide = Pale yellow ppt
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Uses of Chlorine and Fluorine in water treatment

Chlorine

  • Chlorine is used in drinking water as it kills pathogenic bacteria and viruses.
  • Which prevents the outbreak of serious diseases e.g. Typhoid and Cholera.
  • It is applied in its gaseous state to water;
  • Cl2 + H2O --> HOCl + HCl

Fluorine

  • It is added to both water and toothpaste.
  • It only has beneficial effects below 1ppm*
  • It reduces tooth decay cause by cavity formation
  • and in strengthening bones, thus reducing osteoporosis.
  • It is added as flurosilicic acid, sodium fluorosilicate or sodium fluoride.

*1 ppm= one part per million.

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