When conducting his experiment Pavlov choose to use a bell as his neutral stimulus.
Whenever Pavlov provided the dogs with food, he also rang the bell.
After repeating this method several times, the dogs began to salivate just when hearing the bell.
Therefore the learnt the association between the bell and the food, making the response a conditional response and the neutral stimulus a conditioned stimulus.
Pavlov also found that for the dogs to make the associations, the two stimuli (e.g. the bell and the food) had to be presented close together. Pavlov named this the law of temporal contiguity.
If the time between the two stimuli was too great, the learning would not occur and so no association would be made.
Overall classical conditioning (which was later developed by John Watson) involves learning to associate an unconditioned stimulus which brings a particular response, with a new conditioned stimulus so that the new stimulus brings about the same response.
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