Polymers
Sources, classification & manufacture of thermoplastics
- Created by: saraswati
- Created on: 01-05-09 12:29
PLASTICS
plastics..can be natural & synthetic
- versatile often requiring little surface finishing
- can be vacuum formed, injection moulded & blow moulded
- essentially 3 types:
1) Thermoplastics - can be reformed by applying heat (plastic memory)
2) Thermosetting - can't be reformed using heat
3) Elastomers - display elastic properties eg rubber
Thermoplastic are often used as packaging as they share common properties:
- lightwieght
- low cost
- recyclable
- can be printed on
- water-resistant
- impact resistant
- tough & durable
MANUFACTURE: crude oil is refined in fractioning tower to make hydrocarbon naphtha, it's cracked into monomers, these link up to form long chains through polymerisation.
PET - POLYETHLENE TERAPHTHALATE
Recycling ID: 1
PROPERTIES
- excellent transparacy
- very tough
- impenetrable to gases
- can withstand wide range of temperatures
USES
- fizzy drinks bottles
- food containers
- microwaveable food trays
ADVANTAGES
- glass-like transparacy allows products to be seen
- doesnt affect flavour of food products
- ideal for use as packaging for oven ready or microwavable products
HDPE - HIGH DENSITY POLYTHENE
Recycling ID: 2
PROPERTIES
- excellent chemical resistance
- good barrier to water
USES
- bottles & containers for washin up liquids
- cosmetic bottles
- thin sheet packaging
ADVANTAGES
- very suitable for containers designed to hold a wide range of liquids which need to be tough durable & flexible
- very common form of packaging
PVC - POLYVINYL CHLORIDE
Recycling ID: 3
PROPERTIES
- rigid - can be flexible if plasticiers are added
- excellent chemical resistance
- good barrier to water/weather/gases
USES
- shrink wrapping & cling film
- blister packaging
- packaging for toiletries, pharmaceutical products
- food
- confectionary
- water
- fruit juices
ADVANTAGES
- versatile can be used for wide range of products
- chemical resistance makes PVC suitable for batteries or pharmaceutical products
LDPE - LOW DENSITY POLYETHYLENE
Recycling ID : 4
PROPERTIES
- soft
- flexible
- excellent chemical resistance
- good barrier to water but not gases
USES
- stretch wrapping
- liquid proof coatings for card (eg milk cartons)
- carrier & other plastic bags
ADVANTAGES
- when combined with card it becomes very versatile & cost effective material
- plastic bags perform well as an inexpensive method of producing a thin protective layer for a wide range of goods
PP - POLYPROPYLENE
Recycling ID : 5
PROPERTIES
- very flexible
- withstand repeated folding
- can be steralised
USES
- food containers
- bags for dry food products
- bottle crates
- slot-together boxes
- yogurt & margarine tubs
- sweet & snack wrappers
- video cases
ADVANTAGES
- excellent chemical reistance (so PP can be used where other plastics cant
- extremely tough & durable (so wont break if dropped)
- flexible & resistance to fatigue (so material can be manufactured into boxes with 'intergral' hinges which can be folded repeatedly without snapping or tearing
PS - POLYSTYRENE (rigid type eg HIPS, HDPS, LDPS)
Recycling ID : 6
PROPERTIES
- wide range of colours (inc transparent)
- stiff & hard
- can be made impact resistance
USES
- yogurt pots
- CD cases
- disposable cups & cutlery
- bubble packs
- prototype & architectural model
ADVANTAGES
- very suitable for vacuum forming
- very suitable for tough, durable & flexible containers desinged to hold wide range of liquids
PS - POLYSTYRENE (expanded eg styrofoam)
Recycling ID : 6
PROPERTIES
- limited range of colours usually white
- impact resistance
- good heat insulator
- durable
- very buoyant on water
- low water absorption
USES
- take-away packaging
- egg cartons
- fruit, veg & meat trays
- hot drinks cup
- protective packaging for electrical goods
- expanded polystyrene 'peanuts' are used to pack void spaces in boxes to prevent products moving in transit
ADVANTAGES
- doesnt add significant weight
- good heat insulator so it's good for hot food products
- excellent protective layer to absorb impact, preventing damage to valuable & fragile products
ACRYLIC - POLYMETHYLMETHACRYLATE
Recycling ID : 7
PROPERTIES
- wide range of bright colours
- glossy finish
- hard
- brittle
- rigid
- heavy
USES
- high quality containers or closures for perfume products
- signage
- windows point of sale display
ADVANTAGES
- availiable in a wide range of bright colours with a hard,glossy surface finish making it ideal for signage & products which require visual impact
- little finishing required
THERMOSETTING PLASTICS
- set with heat & therafter have little plasticity
- during polymerisation the molecules link side to side & end to end
- covalent bond
- becomes stiff & rigid
- cant be reformed
THERMOPLASTIC
- long tangled chains of molecules, with limited number of smaller cross links
- weak van der waals forces
- heat weakens the bond, the material becomes pliable & easier to mould
- when heat is removed the chains reposition & becomes stiff
POLYESTER RESIN
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