When both atoms in the molecule are the same, and the electrons are equally shared, we can say the centre of charges coincide.
However, when they are not the same one atoms pulls the electron pair closer and this distorts the electron cloud.
This distortion results in the molecule having a small charge.
In a similar way ionic bonds can be distorted by the attraction of the cation for the outer anion.
If this distortion is great it can lead to a charge cloud, which resembles a covalent bond.
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