- Rainwater is naturally weakly acidic because it contains carbonic acid, formed by the reaction between water and carbon dioxide in the atmosphere.
- When the rain falls, it flows over rocks or soaks into the ground and then passes through layers of rock. Compounds from the rocks dissolve into the water.
- Carbonic acid in rainwater reacts with this to produce soluble calcium hydrogencarbonate:
carbonic acid + calcium carbonate → calcium hydrogencarbonate
H2CO3(aq) + CaCO3(s) → Ca(HCO3)2(aq)
- Soft water readily forms lather with soap, but it is more difficult to form lather with hard water. The dissolved calcium ions and magnesium ions in hard water react with the soap to form scum, so more soap is needed. Soapless detergents do not form scum with hard water.
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