Chemistry Definitions F321 F322
Various definitions for chemistry A/S level.
- Created by: beccc
- Created on: 06-05-12 14:41
Relative Isotopic Mass
the mass of an atom of an isotope compared with one twelfth of the mass of carbon-12.
Relative Atomic Mass
the weighted mean mass of an atom of an element when compared with one twelfth of the mass of a carbon-12 atom.
Relative Molecular Mass
the weighted mean mass of a molecule compared with one twelfth of the mass of the atm carbon-12.
Mole
the amount of any substance containing as many particles as there are carbon atoms in exactly 12g of the carbon-12 isotope.
Molar Mass
the mass per mole of a substance.
Empirical Formula
the simplest whole number ratio of atoms of each element present in a compound.
Concentration Of A Solution
the amount of solute dissolved in a solution per 1dm3.
Acid
a species that is a proton donor.
Base
a species that is a proton accepter.
Alkali
a type of base that dissolves in water forming hydroxide iona (OH-).
Salt
any chemical compound formed from an acid when a H+ ion has been replaced by a metal ion or another positive ion.
Water Of Crystallisation
water molecules that form an essential part of the crystaline structure of a compound.
Oxidation Number
a measure of the number of electrons that an atom uses to bond with atoms of another element.
Oxidation
a loss of electrons or an increase in oxidation numer.
Reduction
gain of electrons or a decrease in oxidation number.
Atomic Orbital
a region of space within an atom that can hold up to two electrons, with opposite spins.
Electronegativity
a measure of the attraction of a bonded atom for the pair of electrons in a covalent bond.
Periodicity
a regular periodic variation of properaties of elements with atomic number and position in the Periodic Table.
Thermal Decomposition
the breaking up of a chemical substance with heat in at least two chemical substances.
Displacement Reaction
a reaction in which a more reactive element displaces a less reactive element from an aqueous solution of the latter's ions.
Hydrocarbon
an organic compound which only contains hydrogen and carbon.
Functional Group
the part of the organic molecule which is responsible for its chemical reactions.
General Formula
the simplest algebraic formula of a member of a homologous series.
Structural Isomers
molecules with the same molecular formula but with different structural arrangements of atoms.
Steroeisomers
compounds with the same structural formula, but with different arrangements of atoms in space.
Radical
a species with an unpaired electron.
Homolytic Fission
the breaking of a covalent bond, with one of the bonded electrons going to each atom, forming two radicals.
Heterolytic Fission
the breaking of a covalent bond with both of the bonded electrons going to one of the atoms forming a cation and an anion.
Nucleophile
an atom that is attracted to an electron-deficient centre or atom, where it donates a pair of electrons to form a new covalent bond.
Electrophile
an atom that is attracted to an electron-rich centre or atom, where it accepts a pair of electrons to form a new covalent bond.
Cracking
the breaking down of long-chained saturated hydrocarbons to form a mixture of shorter-chained alkanes and alkenes.
Pi-Bond
the reactive part of a double bond formed above and below the plane of the bonded atoms by sideways overlap of p orbitals.
Esterification
the reaction of an alcohol with a carboxylic acid to produce an ester and water.
Hydrolysis
a reaction with water or aqueous hydroxide ions that breaks a chemical compound into two compounds.
Percentage Yield
actual amount of product / desired amount of product x 100 = (mols)
Atom Economy
molecular mass of desired product / molecular mass of all products x 100
Fragmentation
the process in mass spectrometry that causes a positive ion to split into pieces.
Exothermic
refers to a reaction where the enthalpy of the products is smaller than the enthalpy of the reactants, resulting in heat loss to the surroundings.
Endothermic
refers to a reaction where the enthalpy of the products is greater than the enthalpy of the reactants, resulting in heat being taken in from the surroundings.
Activation Energy
the minimum energy required to start a reaction by the breaking of bonds.
Enthalpy Change of Formation
the enthalpy change that takes place when one mole of a compound is formed from it's elements in their standard states under standard conditions.
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