topic 1 chemistry

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  • topic 1
    • atoms
      • electrons have -1 charge
        • electron move in orbitals
      • most of the mass is concentrated in the nucleus
        • where protons and neutrons are found
    • ions
      • negative ions have more protons than electrons
      • positive ions have fewer electrons than protons
    • isotopes
      • isotopes have the same number of protons but different amonts of neutrons
      • same number and arrangement of electrons
      • differnet physical properties
    • relative mass
      • relative molecular mass (Mr)
        • used for simple molecules
        • add up atomic values for all atoms in the molecule
      • relative atomic mass
        • weighted mean mass of an atom compared to C12
        • can be worked out from isotpic abundances
          • 1. multiply isotopic masses by % abundance, add up results
            • 2. add up results
    • mass spectrometry
      • what samples are made up of
      • shows relative isotopic abundances  on y-axis
      • shows mass or charge on x axis
      • isotpic mass X abundance        add all together and divide by 100 for percentage abundance
    • predicting mass spectra
      • 1. covert % into a decimal
        • 2, make a table showing all isotopes
          • 3. addup abundances (if 2 isoptopes that are the same have been multipleid add the isoptopes together)
            • 4. divide all abundances by the smallest abundance to get a ratio
    • electronic structure
      • electrons move around the nuleus in quantumn shells
        • shells further from the nucleus have more energy than those closer
      • orbtials are the bit of space than electrons move in
        • orbitals in the same subshell have the same amount of energy
          • electrons in each orbitalspin in oposite directions -spin pairing
      • spdf notation
        • s-2electrons  p-6electron    d-10electrons  f-14electrons
          • fill lower energy levels first
            • 4s has a lover energy than 3d
    • electrons
      • at ground state electrons areat their lowest possible energy levels
      • when atoms take in energy they move to a higher energy level, further from the nucleus
    • ionisation energy
      • the removal of one or more atoms from an atom or molecule
      • 1st ionisation energy is the amount of energy needed to remove 1 electron from each mole of gaseous atoms to form 1 mole of gaseous ions.

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