rate of reaction

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  • reaction rates
    • rate of reaction = amount of product used/formed / time (s)
    • increase in pressure (only affects gases)
      • same number of particles are now in a smaller space
        • more frequent successful collisions of reactant particles
          • number of particles in same space increases
          • increased exposure of reactants
    • increase in concentration of reactants
      • number of particles in same space increases
    • increases in temperature
      • particle energy and speed  increases
        • more frequent successful collisions of reactant particles
          • increased exposure of reactants
    • increase in surface area of reactants
      • use a powdered reactant for a larger SA
    • collision theory
      • A reaction will only take place if the particles collide with sufficient energy and correct orientation
      • activation energy
        • minimum energy required
    • catalysts increase rate of reaction by providing an alternate pathway
      • lowers activation energy
    • maxwell-boltzmen distribution curve
      • shape of graph is the same except Ea is reduced
        • catalysts increase rate of reaction by providing an alternate pathway
          • lowers activation energy
        • more molecules with energy excess of Ea
      • different distributions at different temperatures
        • for higher temperatures the graph moves to the right and the peak is lower - more particles with excess Ea
      • no particles have 0 energy so graph doesn't start at 0
      • peak = most probable energy of particles
      • between peak and Ea is the average energy of particles
      • total area doesn't change with condition as the total number of particles stays the same (exc. concentration)
        • increasing concentrationincreses total area - higher peak

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