halogenoalkanes

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  • halogenoalkanes
    • nucleophilic substitution
      • carbon-halogen bond is polar
        • halogens more electronegative
        • the positive dipole on the C makes it prone to attack from nucleophiles
      • nucleophile is an e- pair donor
        • can react with a polar molecule by evicting the functional group and taking it's place
      • alcohol formation
        • hydroxide ion
        • dissolve haloalkane  in ethanol
        • warm aqueous sodium hydroxide
      • nitrile production
        • cyanide ion
        • ethanolic potassium cyanide
      • amine production
        • ammonia molecule
        • excess ammonia, sealed tube and under pressure
        • the amine group has a lone pair of e-
          • can act as a nucleophile
      • substitution more likely for primary haloalkanes
    • elimination reactions
      • forms alkene from halogenoalkane
      • reflux
      • hydroxide ion dissolved in ethanol
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