Getting Metals from Rocks

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  • Getting Metals from Rocks
    • Ores
      • Rock that contains enough metal to make extraction worthwhile
      • Normally oxide of metal
      • Most metals - extracted using chemical reaction
      • Eonpomics of extraction - change
        • Metal price drops - not worth extracting
        • Metal price increases - worth extracting more
        • Improved technology - extract metals not previously worth extracting
    • Reduction
      • Uses carbon
      • Oxygen is removed
        • Iron Oxide + Carbon -> Iron + Carbon Dioxide
      • Position in reactivity series - can be extracted or not
        • Higher than carbon - no
        • Lower than carbon - yes
          • Zinc
          • Iron
          • Tin
          • Copper
    • Electrolysis
      • More reactive than carbon
        • Potassium
        • Sodium
        • Calcium
        • Aluminium
        • Magnesium
      • Electrolysis of molten compounds
      • More expensive than reduction - uses lots of energy
      • Anode and Cathode
        • Anode - Positive - takes away electrons
        • Cathode- negative - gives away electrons
      • Breaking down of a substance using electricity
        • Requires a lot of electricity
          • Electrolyte
            • Metal salt solutions - made from ore
            • Molten metal oxides
            • Free ions - conduct electricity
    • Copper
      • Purified by electrolysis
        • Extracted by reduction
          • Doesn't conduct electricity
            • Meant to be used for wires - needs to conduct electricity
            • Electrolysis makes it pure and conduct electricity
        • Electrons pulled off copper stoms by anode
          • In solution as Cu2+ ions
        • Cu2+ ions near cathode - gain electrons - back into copper atoms
        • Impurities dropped at anode as sludge - pure copper atoms bond to cathode
      • Extracted using Displacement Reaction
        • More reactive metals react more vigorously than less reactive metals
        • Reactive metal in a dissolved metal compound - reactive metal replace less reative metal
      • Copper rich ores are in short supply
        • Recycle as much copper as possible
        • New ways of extracting copper
          • Bioleaching
            • Bacteria - seperate copper in copper sulfide
              • Bacteria gets energy from bond between copper and sulfur
                • Separates copper as leachate - can be extracted
          • Phytomining
            • Grow plants in soil that contains copper
              • Plants can't use or get rid of copper
                • Builds up in leaves
                  • Plants harvested, dried and burned
                    • Copper collected from ash left
          • Traditional methods - damage environment
            • New methods - smaller impact - slower

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