Electrolysis

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  • Created by: aribasxx
  • Created on: 05-03-20 20:10
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  • Electrolysis
    • an electric current is passed through an electrolyte.
      • molten or dissolved ions
    • electroylsis of molten compounds form solids
      • ionic solids can't be electrolysed because ions are in fixed positions and can't move.
      • molten ionic compounds can be electrolysed because ions can move freely and conducts electricity.
      • positive metal ions are reduced to the element of the cathode
        • negative mental ions are oxidises to the element at the anode.
          • 2Br- -----> Br2+ 2e-
        • Pb2+ +2e- --> Pb
    • Metals can be extracted from their ores using electrolysis
      • if metal is too reactive to be reduced by carbon or react with carbon, then electrolysis can be used to extract it.
        • expensive and lots of energy required to melt ore and produce electric current.
    • electrolysis of aqueous solutions
      • in cathode, if  h+ ions and metal ions present, hydrodgen gas will be produced (if metal ions form an elemental element more reactie than hydrodgen.
      • At anode, if OH- ions  and halide ions (Cl-, Br-, I-) arepresent, molecules of chlorine, bromine or iodine will be formed. If no halide ions are present then the OH- ions are discharged and oxygen will be formed.
      • once experiment finished can test gaseous products
        • chlorine bleaches damp litmus paper, white
        • hydrodgen squeaky pop with lighted splint
        • oxygen relights glowing splint
  • Ions move towards electrodes where they react and the compound decomposes.
    • positive ions in electrolyte move towards the cathode and gain electrones ( refuduce)
      • this creates a flow of charge through the electrolyte as ions travel to the electrodes
    • Negative ions in the electrolyte will move towards the anode and lose electrons ( oxidised.
      • this creates a flow of charge through the electrolyte as ions travel to the electrodes
    • an electric current is passed through an electrolyte.
      • molten or dissolved ions

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