carbohydrates

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  • carbohydrates
    • polysaccharides
      • glucose + glucose = maltose
      • glusose + fructose = sucrose
      • glucose + galactose = lactose
        • disaccharides
          • glucose + glucose = maltose
          • glusose + fructose = sucrose
          • formed by the CONDENSATION of two monosaccharides joined by a GLYCOSIDIC bond
      • polysaccharide s are formed by the CONDENSATION of many glucose units
      • glycogen
        • animals convert excess glucose into glycogen
        • branches -> quick energy release
      • starch
        • made from ALPHA glucose
          • glycogen
            • animals convert excess glucose into glycogen
            • branches -> quick energy release
        • plants convert excess glucose into starch for energy storage
          • starch is insoluble and so won't affect water potential - won't cause water to enter cells and swell
          • when plants need more energy they convert the starch back into glucose in a hydrolysis reaction
        • amylose  - unbranched, a-glucose molecules joined by glycosidic bonds (a1-4)
          • coiled -> good for storage
        • amylopectin - branched, a-glucose molecules joined by a1-6 glycosidic bonds
          • side branches make it easier access for enzymes to get to bonds and so glucose released quickly
      • cellulose
        • made from BETA glucose
        • plant cell walls
        • unbranched, straight, parallel chains
          • linked by strong hydrogen bonds which create microfibrils which provide structural support
        • joined via B1-4 glycosidic bonds
    • monosaccharides
      • glucose
        • alpha glucose
          • OH on the left is below H
        • beta glucose
      • fructose
        • all reducing sugars
          • glucose
            • alpha glucose
              • OH on the left is below H
            • beta glucose
          • galactose
      • galactose
      • monosaccharides are carbohydrate monomers
    • non-reducing sugars
      • add HCL (hydrolyse sugar) and sodium hydrogen carbonate (neutralise) then benedict's test
      • tests
        • reducing sugars
          • benedict's test
          • blue -> orange/brown= +
        • iodine test for starch
          • potassium iodide solution
          • brown-> blue/black=+
    • tests
      • reducing sugars
        • benedict's test
        • blue -> orange/brown= +
      • iodine test for starch
        • potassium iodide solution
        • brown-> blue/black=+

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