Ionic Bonding

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  • Ionic Bonding
    • Theory
      • They have high melting points so ions are held together by strong attraction
      • They are often soluble but not non-polar solvents so we know that the particles are charged
      • Don't conduct electricity when solid, only when molten or dissolved = fixed in a solid but free to move in liquid or solution
      • Compounds cannot be shaped = strong repulsion between ions, so ionic compounds are brittle = lattice model
    • Ions
      • Ionic bond = strong electrostatic attraction between two oppositely charges ions
      • They do this to gain a full outer shell
      • Ions are formed when e- are transferred from one atom to another
    • Structures
      • Different ionic compounds have different shaped structures, but they're still ionic lattices
      • Forms because ions are attracted in all directions to ions of opposite charges
      • Ionic crystals are giant lattices = repeated regular structure
    • Size
      • The ionic radius increases down a group as more electron shells are added
      • Isoelectronic ions = different atoms with the same number of electrons
        • Ionic radius decreases down a series as the atomic number increases
        • Higher number of protons = higher attraction to the nucleus = pulled in further
    • Evidence
      • Electrolyse a green copper (II) chromate  (VI) solution on wet filter paper
      • Copper ions move to cathode (end goes blue). Chromate go to anode (yellow)
      • Copper (II) ions = blue in solution, chromate (VI) = yellow
    • Strength
      • Radii
        • Smaller ions can pack closer together, which increases the electrostatic attraction, resulting in a higher melting point
      • Charge
        • Greater charge = stronger electrostatic attraction = higher melting point

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