Organic Reactions and Uses

Created by: pollyisobel
Created on: 27-05-15 19:47

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Alcohol
- Oxidation >
  - Carboxylic Acid
    - Vinegar
  - Primary Alcohol, Oxidising Agent, K2Cr2O7 / H2SO4 catalyst, Reflux
- < Elimination
  - Alkene
    - < Combustion
      - CO2 + H2O
      - Plenty of O2
    - ^ Polymerisation
      - Polymers
        Plastics, fuels, feedstock recycling,
      - 200'c, high pressure
      - TiCl3 or Al(C2H5)2Cl catalyst, 60'c
    - Making plastics, other useful compounds, making butter
  - H3PO4 or H2SO4 conc. Catalysts. Heat
- Oxidation >
  - Aldehyde
    - Flavours
  - K2CR2O7/H2SO4 catalyst, Distil immediately, Primary Alcohol, Oxidising agent
- Hydration >
  - Alkene
    - < Combustion
      - CO2 + H2O
      - Plenty of O2
    - ^ Polymerisation
      - Polymers
        Plastics, fuels, feedstock recycling,
      - 200'c, high pressure
      - TiCl3 or Al(C2H5)2Cl catalyst, 60'c
    - Making plastics, other useful compounds, making butter
  - Steam, H3PO4 catalyst, Heat
- Oxidation >
  - Ketone
  - Secondary alcohol, Oxidising agent, K2Cr2O7 / H2SO4, Heat
- Nucleophilic Substitution
  - Halogenoalkane
    - Radical Substitution >
      - Alkane
        < Cracking
        Zeolite catalyst, 450'c
        
        Hydrogenation v
        H2, Ni catalyst, 150'c
        
        ^ Combustion
        Plenty of O2
        
        < Incomplete Combustion
        CO + H2O
        
        Limited supply of O2
        
        < Reforming
        Cyclic Hydrocarbons
        Promoting more efficient combustion
        
        Fuel
      - UV radiation to form radicals
    - Electrophilic Addition v
      - Halogens, room temperature
    - Hydrolysis
      - Alcohol
        Oxidation >
        Carboxylic Acid
        Vinegar
        
        Primary Alcohol, Oxidising Agent, K2Cr2O7 / H2SO4 catalyst, Reflux
        
        < Elimination
        H3PO4 or H2SO4 conc. Catalysts. Heat
        
        Oxidation >
        Aldehyde
        Flavours
        
        K2CR2O7/H2SO4 catalyst, Distil immediately, Primary Alcohol, Oxidising agent
        
        Hydration >
        Steam, H3PO4 catalyst, Heat
        
        Oxidation >
        Ketone
        
        Secondary alcohol, Oxidising agent, K2Cr2O7 / H2SO4, Heat
        
        Nucleophilic Substitution
        Halogenoalkane
        Radical Substitution >
        Alkane
        < Cracking
        Zeolite catalyst, 450'c
        
        Hydrogenation v
        H2, Ni catalyst, 150'c
        
        ^ Combustion
        Plenty of O2
        
        < Incomplete Combustion
        CO + H2O
        
        Limited supply of O2
        
        < Reforming
        Cyclic Hydrocarbons
        Promoting more efficient combustion
        
        Fuel
        
        UV radiation to form radicals
        
        Electrophilic Addition v
        Halogens, room temperature
        
        Hydrolysis
        Heat, reflux
        
        Making polymers, fridges, polystyrene foam bubbles, propellants, blowing agents, solvents
        
        Reflux
        
        ^ Combustion
        CO2 + H2O
        
        Plenty of O2
        
        Esterification v
        Ester
        Adhesives, solvents, flavours and fragrances
        
        H2SO4 conc catalyst, heat
        
        Dehydration
        Concentarted H2SO4 or H3PO4 catalysts
        
        Alcoholic drinks, fuel, solvent chemical feedstock
      - Heat, reflux
    - Making polymers, fridges, polystyrene foam bubbles, propellants, blowing agents, solvents
  - Reflux
- ^ Combustion
  - CO2 + H2O
  - Plenty of O2
- Esterification v
  - Ester
    - Adhesives, solvents, flavours and fragrances
  - H2SO4 conc catalyst, heat
- Dehydration
  - Concentarted H2SO4 or H3PO4 catalysts
- Alcoholic drinks, fuel, solvent chemical feedstock

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Organic Reactions and Uses

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